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ansa-zirconocene complexes with modified benzindenyl ligands : syntheses, crystal structure, and properties as propene polymerization catalysts

ansa-zirconocene complexes with modified benzindenyl ligands : syntheses, crystal structure, and properties as propene polymerization catalysts

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SCHNEIDER, Nicole, Monika E. HUTTENLOCH, Udo STEHLING, Robin KIRSTEN, Frank SCHAPER, Hans-Herbert BRINTZINGER, 1997. ansa-zirconocene complexes with modified benzindenyl ligands : syntheses, crystal structure, and properties as propene polymerization catalysts. In: Organometallics. 16(15), pp. 3413-3420. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om970131h

@article{Schneider1997ansaz-23751, title={ansa-zirconocene complexes with modified benzindenyl ligands : syntheses, crystal structure, and properties as propene polymerization catalysts}, year={1997}, doi={10.1021/om970131h}, number={15}, volume={16}, issn={0276-7333}, journal={Organometallics}, pages={3413--3420}, author={Schneider, Nicole and Huttenloch, Monika E. and Stehling, Udo and Kirsten, Robin and Schaper, Frank and Brintzinger, Hans-Herbert} }

2013-06-24T17:00:28Z Schaper, Frank Kirsten, Robin Stehling, Udo terms-of-use Schneider, Nicole Stehling, Udo Schneider, Nicole Huttenloch, Monika E. Huttenloch, Monika E. eng 1997 Organometallics ; 16 (1997), 15. - S. 3413-3420 Schaper, Frank As modifications of the effective catalyst precursor [dimethylsilanediylbis(benz[e]indenyl)]zirconium dichloride, the ansa-zirconocene complexes Me<sub>2</sub>Si(cyclopenta[c]phenanthryl)<sub>2</sub>ZrCl<sub>2</sub>, Me<sub>2</sub>Si(cyclopenta[l]phenanthryl)<sub>2</sub>ZrCl<sub>2</sub>, Me<sub>2</sub>Si(2-methylcyclopenta[l]phenanthryl)<sub>2</sub>ZrCl<sub>2</sub>, and Me<sub>2</sub>Si(2-methyltetrahydrobenz[e]indenyl)<sub>2</sub>ZrCl<sub>2</sub> have been synthesized. When activated by methylaluminoxane (MAO), these complexes give highly active catalysts for the polymerization of propene to polymers with high isotacticities and molecular weights. Brintzinger, Hans-Herbert ansa-zirconocene complexes with modified benzindenyl ligands : syntheses, crystal structure, and properties as propene polymerization catalysts Brintzinger, Hans-Herbert 2013-06-24T17:00:28Z Kirsten, Robin

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