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The Reaction of alpha-Chlorocarbenium Salts with Nitriles : Formation of Chloro-Substituted 2-Azoniaallene Salts

The Reaction of alpha-Chlorocarbenium Salts with Nitriles : Formation of Chloro-Substituted 2-Azoniaallene Salts

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JOCHIMS, Johannes C., Helmut FISCHER, Atef HAMED, Tran HUU-PHUOC, Josef HOFMANN, Helmut FISCHER, 1989. The Reaction of alpha-Chlorocarbenium Salts with Nitriles : Formation of Chloro-Substituted 2-Azoniaallene Salts. In: Synthesis. 1989(12), pp. 918-922. ISSN 0039-7881. eISSN 1437-210X

@article{Jochims1989React-23551, title={The Reaction of alpha-Chlorocarbenium Salts with Nitriles : Formation of Chloro-Substituted 2-Azoniaallene Salts}, year={1989}, doi={10.1055/s-1989-27430}, number={12}, volume={1989}, issn={0039-7881}, journal={Synthesis}, pages={918--922}, author={Jochims, Johannes C. and Fischer, Helmut and Hamed, Atef and Huu-Phuoc, Tran and Hofmann, Josef and Fischer, Helmut} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/23551"> <dc:creator>Fischer, Helmut</dc:creator> <dc:creator>Huu-Phuoc, Tran</dc:creator> <dc:contributor>Huu-Phuoc, Tran</dc:contributor> <dc:contributor>Hamed, Atef</dc:contributor> <dc:rights>deposit-license</dc:rights> <dcterms:title>The Reaction of alpha-Chlorocarbenium Salts with Nitriles : Formation of Chloro-Substituted 2-Azoniaallene Salts</dcterms:title> <dc:contributor>Fischer, Helmut</dc:contributor> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-07-04T06:52:15Z</dc:date> <dc:creator>Jochims, Johannes C.</dc:creator> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/23551"/> <dc:language>eng</dc:language> <dc:creator>Hofmann, Josef</dc:creator> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-07-04T06:52:15Z</dcterms:available> <dc:contributor>Hofmann, Josef</dc:contributor> <dc:creator>Hamed, Atef</dc:creator> <dc:contributor>Jochims, Johannes C.</dc:contributor> <dcterms:bibliographicCitation>Synthesis : journal of synthetic organic chemistry ; (1989), 12. - S. 918-922</dcterms:bibliographicCitation> <dcterms:rights rdf:resource="http://nbn-resolving.org/urn:nbn:de:bsz:352-20140905103605204-4002607-1"/> <dcterms:abstract xml:lang="eng">Diaryl or arylchloro substituted α-chlorocarbenium salts react with benzonitriles or dimethylcyanamide to afford chloro substituted 2-azoniaallene salts 10a, b, 11c. An X-ray structural analysis confirms the constitution of one of these salts (11c). Substitution of the chlorine atoms in 1,3-dichloro-1,3-diphenyl-2-azoniaallene hexachloroantimonate (10a) by the nucleophiles water, p-cresol, p-toluidine, diethylamine, hydrazine, methyl-, phenyl-, 2.4,6-trichlorophenylhydrazine, hydroxylamine, N-phenylhydroxylamine, 1,3-dimethylurea, and ethyl allophanate have been carried out affording heterocycles and open-chain compounds 13-21.</dcterms:abstract> <dcterms:issued>1989</dcterms:issued> </rdf:Description> </rdf:RDF>

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