Reversal of the stereoselectivity of [4 + 2]-cycloadditions by co-ordination of the heterodienophile to a transition metal fragment

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1989
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Treier, Kornelia
Gerbing, Ulrike
Hofmann, Josef
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Journal of the Chemical Society, Chemical Communications. 1989(10), pp. 667-668. ISSN 0022-4936. Available under: doi: 10.1039/C39890000667
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Co-ordination of thio- and selenoaldehydes to a pentacarbonylmetal fragment results in a reversal of the endo selectivity in Diels–Alder reactions with conjugated cyclic dienes giving predominantly exo adducts.

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ISO 690FISCHER, Helmut, Kornelia TREIER, Ulrike GERBING, Josef HOFMANN, 1989. Reversal of the stereoselectivity of [4 + 2]-cycloadditions by co-ordination of the heterodienophile to a transition metal fragment. In: Journal of the Chemical Society, Chemical Communications. 1989(10), pp. 667-668. ISSN 0022-4936. Available under: doi: 10.1039/C39890000667
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@article{Fischer1989Rever-23549,
  year={1989},
  doi={10.1039/C39890000667},
  title={Reversal of the stereoselectivity of [4 + 2]-cycloadditions by co-ordination of the heterodienophile to a transition metal fragment},
  number={10},
  issn={0022-4936},
  journal={Journal of the Chemical Society, Chemical Communications},
  pages={667--668},
  author={Fischer, Helmut and Treier, Kornelia and Gerbing, Ulrike and Hofmann, Josef}
}
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