N-acyliminium salts from the reaction of nitrilium salts with aldehydes

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JOCHIMS, Johannes, Michael O. GLOCKER, Josef HOFMANN, Helmut FISCHER, 1991. N-acyliminium salts from the reaction of nitrilium salts with aldehydes. In: Tetrahedron. 47(2), pp. 205-218. ISSN 0040-4020. eISSN 1464-5416

@article{Jochims1991N-acy-23488, title={N-acyliminium salts from the reaction of nitrilium salts with aldehydes}, year={1991}, doi={10.1016/S0040-4020(01)80917-0}, number={2}, volume={47}, issn={0040-4020}, journal={Tetrahedron}, pages={205--218}, author={Jochims, Johannes and Glocker, Michael O. and Hofmann, Josef and Fischer, Helmut} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/23488"> <dc:creator>Glocker, Michael O.</dc:creator> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-07-01T14:21:28Z</dcterms:available> <dc:contributor>Fischer, Helmut</dc:contributor> <dc:contributor>Hofmann, Josef</dc:contributor> <dc:language>eng</dc:language> <dcterms:rights rdf:resource="http://nbn-resolving.org/urn:nbn:de:bsz:352-20140905103605204-4002607-1"/> <dcterms:abstract xml:lang="eng">The nitrilium hexachloroantimonates 2a,d,g,p react with aromatic aldehydes to give isolable N-acyliminium hexachloroantimonates 10a-m. The N-aroyliminium salts (10g-m) and acyliminium salts with an aliphatic N-acyl group (10a-f) are of remarkably different stability. Contrary to the N-aroyliminium salts, compounds 10a-f are unstable in solution, e. g. react immediately with acetonitrile. With excess of aldehyde 10n,o give insertion products of the probable structures 12a,b. For 10b,f X-ray structural analyses have been carried out. The N-acylcyanamidium hexachloroantimonate 2p reacts with aldehydes to give new classes of cyclic N-acyliminium salts 13a-f, and 14f, respectively.</dcterms:abstract> <dc:creator>Jochims, Johannes</dc:creator> <dc:rights>deposit-license</dc:rights> <dcterms:bibliographicCitation>Tetrahedron ; 47 (1991), 2. - S. 205-218</dcterms:bibliographicCitation> <dc:contributor>Jochims, Johannes</dc:contributor> <dc:creator>Hofmann, Josef</dc:creator> <dcterms:title>N-acyliminium salts from the reaction of nitrilium salts with aldehydes</dcterms:title> <dcterms:issued>1991</dcterms:issued> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/23488"/> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-07-01T14:21:28Z</dc:date> <dc:contributor>Glocker, Michael O.</dc:contributor> <dc:creator>Fischer, Helmut</dc:creator> </rdf:Description> </rdf:RDF>

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