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Synthese und Röntgenstrukturanalyse eines zweikernigen Bis(ansa-carben)-Komplexes

Synthese und Röntgenstrukturanalyse eines zweikernigen Bis(ansa-carben)-Komplexes

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FISCHER, Helmut, Joachim SCHLEU, Carsten TROLL, 1994. Synthese und Röntgenstrukturanalyse eines zweikernigen Bis(ansa-carben)-Komplexes. In: Journal of Organometallic Chemistry. 464(1), pp. 83-86. ISSN 0022-328X. Available under: doi: 10.1016/0022-328X(94)87013-6

@article{Fischer1994Synth-23389, title={Synthese und Röntgenstrukturanalyse eines zweikernigen Bis(ansa-carben)-Komplexes}, year={1994}, doi={10.1016/0022-328X(94)87013-6}, number={1}, volume={464}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={83--86}, author={Fischer, Helmut and Schleu, Joachim and Troll, Carsten} }

1994 terms-of-use Fischer, Helmut Journal of Organometallic Chemistry ; 464 (1994),1. - S. 83-86 Troll, Carsten 2013-06-26T10:36:23Z Synthese und Röntgenstrukturanalyse eines zweikernigen Bis(ansa-carben)-Komplexes Fischer, Helmut eng The cationic dicarbonyl(cyclopentadienyl)(methylcarbyne)manganese complex, [(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)(CO)<sub>2</sub>Mn≡CMe]BCl<sub>4</sub>, reacts with dimethyl cyanamide, Me<sub>2</sub>NC≡N, to give the binuclear bis(ansa-dimethylaminocarbene) complex 4 containing chelating η<sup>1</sup>,η<sup>5</sup>-(dimethylamino)[(cyclopentadienyl) (organyl)methylamino]carbene ligands. The two ansa-carbene ligands are connected via a CH group. The structure of the complex is established by an X-ray analysis. Schleu, Joachim 2013-06-26T10:36:23Z Troll, Carsten Schleu, Joachim

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