Synthesis of the first 2H-selenete complexes, decomplexation and dimerization to dihydro-1,2-diselenine
| Publikationstyp: | Zeitschriftenartikel |
| Autor/innen: | Fischer, Helmut; Treier, Kornelia; Troll, Carsten; Stumpf, Rüdiger |
| Erscheinungsjahr: | 1995 |
| Erschienen in: | Journal of the Chemical Society, Chemical Communications ; 1995, 23. - S. 2461-2463. - ISSN 0022-4936 |
| DOI (zitierfähiger Link): | https://dx.doi.org/10.1039/C39950002461 |
| Zusammenfassung: |
Pentacarbonyltungsten-coordinated selenobenzaldehydes, (CO)5W[Se[double bond, length half m-dash]C(C6H4R-p)H](R = QMe, H, CF3), react with ButS–C[triple bond, length half m-dash]C–SBut by addition of the C[triple bond, length half m-dash]C to the Se[double bond, length half m-dash]C bond to give 2H-selenete complexes; treatment of the selenete complex (R[double bond, length half m-dash]H) with NEt4Br affords the uncoordinated 2H-selenete and a 3,4-dihydro-1,2-diselenine.
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| Fachgebiet (DDC): | 540 Chemie |
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FISCHER, Helmut, Kornelia TREIER, Carsten TROLL, Rüdiger STUMPF, 1995. Synthesis of the first 2H-selenete complexes, decomplexation and dimerization to dihydro-1,2-diselenine. In: Journal of the Chemical Society, Chemical Communications(23), pp. 2461-2463. ISSN 0022-4936. Available under: doi: 10.1039/C39950002461
@article{Fischer1995Synth-23175, title={Synthesis of the first 2H-selenete complexes, decomplexation and dimerization to dihydro-1,2-diselenine}, year={1995}, doi={10.1039/C39950002461}, number={23}, issn={0022-4936}, journal={Journal of the Chemical Society, Chemical Communications}, pages={2461--2463}, author={Fischer, Helmut and Treier, Kornelia and Troll, Carsten and Stumpf, Rüdiger} }
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