Synthesis of the first 2H-selenete complexes, decomplexation and dimerization to dihydro-1,2-diselenine
| Type of Publication: | Journal article |
| Author: | Fischer, Helmut; Treier, Kornelia; Troll, Carsten; Stumpf, Rüdiger |
| Year of publication: | 1995 |
| Published in: | Journal of the Chemical Society, Chemical Communications ; 1995, 23. - pp. 2461-2463. - ISSN 0022-4936 |
| DOI (citable link): | https://dx.doi.org/10.1039/C39950002461 |
| Summary: |
Pentacarbonyltungsten-coordinated selenobenzaldehydes, (CO)5W[Se[double bond, length half m-dash]C(C6H4R-p)H](R = QMe, H, CF3), react with ButS–C[triple bond, length half m-dash]C–SBut by addition of the C[triple bond, length half m-dash]C to the Se[double bond, length half m-dash]C bond to give 2H-selenete complexes; treatment of the selenete complex (R[double bond, length half m-dash]H) with NEt4Br affords the uncoordinated 2H-selenete and a 3,4-dihydro-1,2-diselenine.
|
| Subject (DDC): | 540 Chemistry |
Cite This
Files in this item
| Files | Size | Format | View |
|---|---|---|---|
|
There are no files associated with this item. |
|||
FISCHER, Helmut, Kornelia TREIER, Carsten TROLL, Rüdiger STUMPF, 1995. Synthesis of the first 2H-selenete complexes, decomplexation and dimerization to dihydro-1,2-diselenine. In: Journal of the Chemical Society, Chemical Communications(23), pp. 2461-2463. ISSN 0022-4936. Available under: doi: 10.1039/C39950002461
@article{Fischer1995Synth-23175, title={Synthesis of the first 2H-selenete complexes, decomplexation and dimerization to dihydro-1,2-diselenine}, year={1995}, doi={10.1039/C39950002461}, number={23}, issn={0022-4936}, journal={Journal of the Chemical Society, Chemical Communications}, pages={2461--2463}, author={Fischer, Helmut and Treier, Kornelia and Troll, Carsten and Stumpf, Rüdiger} }
<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/23175"> <dc:creator>Fischer, Helmut</dc:creator> <dcterms:abstract xml:lang="eng">Pentacarbonyltungsten-coordinated selenobenzaldehydes, (CO)5W[Se[double bond, length half m-dash]C(C6H4R-p)H](R = QMe, H, CF3), react with ButS–C[triple bond, length half m-dash]C–SBut by addition of the C[triple bond, length half m-dash]C to the Se[double bond, length half m-dash]C bond to give 2H-selenete complexes; treatment of the selenete complex (R[double bond, length half m-dash]H) with NEt4Br affords the uncoordinated 2H-selenete and a 3,4-dihydro-1,2-diselenine.</dcterms:abstract> <dc:contributor>Stumpf, Rüdiger</dc:contributor> <dc:contributor>Fischer, Helmut</dc:contributor> <dc:contributor>Troll, Carsten</dc:contributor> <dcterms:issued>1995</dcterms:issued> <dcterms:bibliographicCitation>Journal of the Chemical Society, Chemical Communications ; (1995), 23. - S. 2461-2463</dcterms:bibliographicCitation> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-05-21T09:02:10Z</dcterms:available> <dcterms:title>Synthesis of the first 2H-selenete complexes, decomplexation and dimerization to dihydro-1,2-diselenine</dcterms:title> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-05-21T09:02:10Z</dc:date> <dc:creator>Troll, Carsten</dc:creator> <dc:language>eng</dc:language> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/23175"/> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <foaf:homepage rdf:resource="http://localhost:8080/jspui"/> <dc:creator>Stumpf, Rüdiger</dc:creator> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dc:contributor>Treier, Kornelia</dc:contributor> <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/> <dc:rights>terms-of-use</dc:rights> <dc:creator>Treier, Kornelia</dc:creator> </rdf:Description> </rdf:RDF>
This item appears in the following Collection(s)
Search KOPS
Browse
My Account
