KOPS - The Institutional Repository of the University of Konstanz

On the Way to Heptahexaenylidene Complexes :  Trapping of an Intermediate with the Novel M=C=C=C=C=C=C=CR2 Moiety

On the Way to Heptahexaenylidene Complexes :  Trapping of an Intermediate with the Novel M=C=C=C=C=C=C=CR2 Moiety

Cite This

Files in this item

Files Size Format View

There are no files associated with this item.

ROTH, Gerhard, Helmut FISCHER, 1996. On the Way to Heptahexaenylidene Complexes :  Trapping of an Intermediate with the Novel M=C=C=C=C=C=C=CR2 Moiety. In: Organometallics. 15(26), pp. 5766-5768. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om960605x

@article{Roth1996Hepta-23056, title={On the Way to Heptahexaenylidene Complexes :  Trapping of an Intermediate with the Novel M=C=C=C=C=C=C=CR2 Moiety}, year={1996}, doi={10.1021/om960605x}, number={26}, volume={15}, issn={0276-7333}, journal={Organometallics}, pages={5766--5768}, author={Roth, Gerhard and Fischer, Helmut} }

<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/23056"> <dcterms:bibliographicCitation>Organometallics ; 15 (1996), 26. - S. 5766–5768</dcterms:bibliographicCitation> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/23056"/> <dcterms:title>On the Way to Heptahexaenylidene Complexes :  Trapping of an Intermediate with the Novel M=C=C=C=C=C=C=CR2 Moiety</dcterms:title> <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/> <foaf:homepage rdf:resource="http://localhost:8080/jspui"/> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dc:creator>Fischer, Helmut</dc:creator> <dc:contributor>Roth, Gerhard</dc:contributor> <dcterms:abstract xml:lang="eng">Sequential treatment of the in situ generated heptatriyne Me3SiCCCCCCC(NMe2)3 with n-BuLi, (CO)5W[THF], and BF3·OEt2 affords the first alkenyl-substituted pentatetraenylidene complex, (CO)5WC CCCC(NMe2)C(H)C(NMe2)2 (4), via addition of dimethylamine to the CεCζ bond of the intermediate heptahexaenylidene complex (CO)5WCαCβCγCδ CεCζCη(NMe2)2. In addition, the alkynyl(butatrienyl)carbene complex (CO)5WC(CCSiMe3)C(Bu)C CC(NMe2)2 (5) is formed.</dcterms:abstract> <dc:language>eng</dc:language> <dcterms:issued>1996</dcterms:issued> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-06-12T10:43:42Z</dc:date> <dc:creator>Roth, Gerhard</dc:creator> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dc:rights>terms-of-use</dc:rights> <dc:contributor>Fischer, Helmut</dc:contributor> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-06-12T10:43:42Z</dcterms:available> </rdf:Description> </rdf:RDF>

This item appears in the following Collection(s)

Search KOPS


Browse

My Account