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Lanthanide Complexes with Carbacylamidophosphates : The First Registration of Chelate Coordination of the Neutral Ligand Form in the Structure of Di-(N,N'-tetramethyl-N''-benzoylphosphoryltriamide) cerium(III) Nitrate

Lanthanide Complexes with Carbacylamidophosphates : The First Registration of Chelate Coordination of the Neutral Ligand Form in the Structure of Di-(N,N'-tetramethyl-N''-benzoylphosphoryltriamide) cerium(III) Nitrate

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GUBINA, Katerina, Vladimir OVCHYNNIKOV, Vladimir AMIRKHANOV, Helmut FISCHER, Rüdiger STUMPF, Viktor SKOPENKO, 2000. Lanthanide Complexes with Carbacylamidophosphates : The First Registration of Chelate Coordination of the Neutral Ligand Form in the Structure of Di-(N,N'-tetramethyl-N''-benzoylphosphoryltriamide) cerium(III) Nitrate. In: Zeitschrift für Naturforschung B. 55, pp. 576-582. ISSN 0932-0776. eISSN 1865-7117

@article{Gubina2000Lanth-22969, title={Lanthanide Complexes with Carbacylamidophosphates : The First Registration of Chelate Coordination of the Neutral Ligand Form in the Structure of Di-(N,N'-tetramethyl-N''-benzoylphosphoryltriamide) cerium(III) Nitrate}, year={2000}, volume={55}, issn={0932-0776}, journal={Zeitschrift für Naturforschung B}, pages={576--582}, author={Gubina, Katerina and Ovchynnikov, Vladimir and Amirkhanov, Vladimir and Fischer, Helmut and Stumpf, Rüdiger and Skopenko, Viktor} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/22969"> <dcterms:rights rdf:resource="http://nbn-resolving.org/urn:nbn:de:bsz:352-20140905103605204-4002607-1"/> <dc:language>eng</dc:language> <dc:creator>Fischer, Helmut</dc:creator> <dc:contributor>Amirkhanov, Vladimir</dc:contributor> <dcterms:title>Lanthanide Complexes with Carbacylamidophosphates : The First Registration of Chelate Coordination of the Neutral Ligand Form in the Structure of Di-(N,N'-tetramethyl-N''-benzoylphosphoryltriamide) cerium(III) Nitrate</dcterms:title> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/22969"/> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-06-05T09:55:12Z</dc:date> <dc:contributor>Stumpf, Rüdiger</dc:contributor> <dc:rights>deposit-license</dc:rights> <dc:contributor>Gubina, Katerina</dc:contributor> <dc:creator>Gubina, Katerina</dc:creator> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-06-05T09:55:12Z</dcterms:available> <dc:contributor>Fischer, Helmut</dc:contributor> <dc:contributor>Ovchynnikov, Vladimir</dc:contributor> <dcterms:bibliographicCitation>Zeitschrift für Naturforschung B ; 55 (2000). - S. 576-582</dcterms:bibliographicCitation> <dc:creator>Stumpf, Rüdiger</dc:creator> <dcterms:abstract xml:lang="eng">The coordination compounds of the general formula Ln(HL)2(NO3)3, (where Ln = La - Eu (without Pm), HL = C6H5C(O)NHP(O)[N(CH3)2]2, N,N'-tetramethyl-N''-benzoylphosphoryltriamide) have been synthesized and characterized by means of IR, UV-VIS, 1H, 31P NMR spectroscopy, and X-ray analysis. The complexes are isostructural according to X-ray powder diffraction studies. The crystal structure of the cerium(III) complex has been determined. Crystal data: monoclinic, P21/c, with a = 10.503(9), b = 15.62(2), c = 21.91(2) A° , = 99.56(8) , Z = 4, V = 3546(6) °A3, R1 = 0.0550, wR2 = 0.1383 for 6970 unique reflections used. The complex has a molecular structure. Neutral phosphoryltriamide ligands are coordinated to the metal ion in a bidentate manner via phosphoryl and carbonyl oxygen atoms with formation of six membered chelate rings. The coordination polyhedron of the Ce atom is a sphenocorona; C.N. = 10 (4 O[HL] + 6 O[NO3 􀀀]).</dcterms:abstract> <dcterms:issued>2000</dcterms:issued> <dc:creator>Ovchynnikov, Vladimir</dc:creator> <dc:creator>Amirkhanov, Vladimir</dc:creator> <dc:creator>Skopenko, Viktor</dc:creator> <dc:contributor>Skopenko, Viktor</dc:contributor> </rdf:Description> </rdf:RDF>

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