Homo-metathesis of vinylsilanes catalysed by ruthenium carbene complexes

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PIETRASZUK, Cezary, Bogdan MARCINIEC, Szymon ROGALSKI, Helmut FISCHER, 2005. Homo-metathesis of vinylsilanes catalysed by ruthenium carbene complexes. In: Journal of Molecular Catalysis A: Chemical. ISSN 1381-1169

@article{Pietraszuk2005Homo--22835, title={Homo-metathesis of vinylsilanes catalysed by ruthenium carbene complexes}, year={2005}, doi={10.1016/j.molcata.2005.06.036}, issn={1381-1169}, journal={Journal of Molecular Catalysis A: Chemical}, author={Pietraszuk, Cezary and Marciniec, Bogdan and Rogalski, Szymon and Fischer, Helmut} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/22835"> <dc:contributor>Rogalski, Szymon</dc:contributor> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-05-24T07:44:56Z</dcterms:available> <dc:contributor>Fischer, Helmut</dc:contributor> <dcterms:title>Homo-metathesis of vinylsilanes catalysed by ruthenium carbene complexes</dcterms:title> <dc:creator>Rogalski, Szymon</dc:creator> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/22835"/> <dcterms:abstract xml:lang="eng">Effective homo-metathesis of a series of dichloro-substituted vinylsilanes H2C = C(H)SiCl2R (where R = Me, OSiMe3, C6H5, C6H4–Me-4, C6H4–CF3-4) in the presence of second generation Grubbs catalyst [Cl2(PCy3)(IMesH2)Ru(=CHPh)] (I) and Hoveyda–Grubbs catalyst (II) leads to selective formation of E-1,2-bis(silyl)ethenes and ethene. On the basis of the results of experiments with deuterium-labelled reagents, a metallacarbene mechanism has been suggested for these reactions.</dcterms:abstract> <dcterms:rights rdf:resource="http://nbn-resolving.org/urn:nbn:de:bsz:352-20140905103605204-4002607-1"/> <dc:contributor>Marciniec, Bogdan</dc:contributor> <dc:contributor>Pietraszuk, Cezary</dc:contributor> <dc:creator>Pietraszuk, Cezary</dc:creator> <dc:language>eng</dc:language> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-05-24T07:44:56Z</dc:date> <dc:rights>deposit-license</dc:rights> <dcterms:bibliographicCitation>Journal of Molecular Catalysis : A, Chemical ; 240 (2005), 1-2. - S. 67-71</dcterms:bibliographicCitation> <dc:creator>Marciniec, Bogdan</dc:creator> <dc:creator>Fischer, Helmut</dc:creator> <dcterms:issued>2005</dcterms:issued> </rdf:Description> </rdf:RDF>

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