KOPS - Das Institutionelle Repositorium der Universität Konstanz

Synthesis, Spectroelectrochemistry and Electronic Structure Calculations of 4-(2-Ferrocenylvinyl)-[2.2]-paracyclophane and 4,12-di-(2-Ferrocenylvinyl)-[2.2]-paracyclophane

Synthesis, Spectroelectrochemistry and Electronic Structure Calculations of 4-(2-Ferrocenylvinyl)-[2.2]-paracyclophane and 4,12-di-(2-Ferrocenylvinyl)-[2.2]-paracyclophane

Zitieren

Dateien zu dieser Ressource

Prüfsumme: MD5:efb4e36ccd7968d99d23f0149c78dcd1

MÜCKE, Philipp, Rainer F. WINTER, Igor NOVAK, Konrad KOWALSKI, 2012. Synthesis, Spectroelectrochemistry and Electronic Structure Calculations of 4-(2-Ferrocenylvinyl)-[2.2]-paracyclophane and 4,12-di-(2-Ferrocenylvinyl)-[2.2]-paracyclophane. In: Journal of Organometallic Chemistry. 717, pp. 14-22. ISSN 0022-328X. eISSN 0022-328X

@article{Mucke2012Synth-20694, title={Synthesis, Spectroelectrochemistry and Electronic Structure Calculations of 4-(2-Ferrocenylvinyl)-[2.2]-paracyclophane and 4,12-di-(2-Ferrocenylvinyl)-[2.2]-paracyclophane}, year={2012}, doi={10.1016/j.jorganchem.2012.07.020}, volume={717}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={14--22}, author={Mücke, Philipp and Winter, Rainer F. and Novak, Igor and Kowalski, Konrad} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/20694"> <dc:contributor>Kowalski, Konrad</dc:contributor> <dcterms:rights rdf:resource="http://nbn-resolving.org/urn:nbn:de:bsz:352-20140905103605204-4002607-1"/> <dc:creator>Winter, Rainer F.</dc:creator> <dc:creator>Mücke, Philipp</dc:creator> <dc:language>eng</dc:language> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2012-10-19T07:03:10Z</dc:date> <dc:contributor>Novak, Igor</dc:contributor> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/20694"/> <dc:rights>deposit-license</dc:rights> <dcterms:title>Synthesis, Spectroelectrochemistry and Electronic Structure Calculations of 4-(2-Ferrocenylvinyl)-[2.2]-paracyclophane and 4,12-di-(2-Ferrocenylvinyl)-[2.2]-paracyclophane</dcterms:title> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2013-10-31T23:25:04Z</dcterms:available> <dc:creator>Novak, Igor</dc:creator> <dcterms:bibliographicCitation>Journal of organometallic chemistry ; 717 (2012). - S. 14-22</dcterms:bibliographicCitation> <dcterms:abstract xml:lang="eng">Abstract: 4,12-di-(2-ferrocenylvinyl)-[2.2]-paracyclophane 2 has been prepared and investigated with respect to its electrochemical and UV/Vis/NIR spectroelectrochemical properties. Cyclic and square wave voltammetric measurements show two consecutive one-electron oxidations with a moderate redox splitting of 112(±3) mV for the individual Fc/Fc+ couples. In spite of this redox splitting, radical cation 2•+ is a class I mixed-valent system with no detectable electronic coupling between the individual redox sites as is shown by the comparison of the Vis/NIR spectra of 2•+, 22+ and the radical cation of 4-(2-ferrocenylvinyl)-[2.2]-paracyclophane, 4•+. The NIR bands observed for the oxidized forms have been assigned as ferrocene-based d-d transitions by quantum chemical calculations.</dcterms:abstract> <dc:contributor>Mücke, Philipp</dc:contributor> <dc:contributor>Winter, Rainer F.</dc:contributor> <dc:creator>Kowalski, Konrad</dc:creator> <dcterms:issued>2012</dcterms:issued> </rdf:Description> </rdf:RDF>

Dateiabrufe seit 01.10.2014 (Informationen über die Zugriffsstatistik)

synthesis electronic muecke winter.pdf 417

Das Dokument erscheint in:

KOPS Suche


Stöbern

Mein Benutzerkonto