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Giant permittivity and dynamic mobility observed for spherical polyelectrolyte brushes

Giant permittivity and dynamic mobility observed for spherical polyelectrolyte brushes

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JIMÉNEZ, Maria Luisa, Angel DELGADO, Silvia AHUALLI, Marius HOFFMANN, Alexander WITTEMANN, Matthias BALLAUFF, 2011. Giant permittivity and dynamic mobility observed for spherical polyelectrolyte brushes. In: Soft Matter. 7(8), pp. 3758-3762. ISSN 1744-683X. Available under: doi: 10.1039/C0SM01544J

@article{Jimenez2011Giant-20181, title={Giant permittivity and dynamic mobility observed for spherical polyelectrolyte brushes}, year={2011}, doi={10.1039/C0SM01544J}, number={8}, volume={7}, issn={1744-683X}, journal={Soft Matter}, pages={3758--3762}, author={Jiménez, Maria Luisa and Delgado, Angel and Ahualli, Silvia and Hoffmann, Marius and Wittemann, Alexander and Ballauff, Matthias} }

<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/20181"> <foaf:homepage rdf:resource="http://localhost:8080/jspui"/> <dc:creator>Hoffmann, Marius</dc:creator> <dcterms:title>Giant permittivity and dynamic mobility observed for spherical polyelectrolyte brushes</dcterms:title> <dc:creator>Ballauff, Matthias</dc:creator> <dc:rights>deposit-license</dc:rights> <dc:contributor>Ahualli, Silvia</dc:contributor> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dcterms:issued>2011</dcterms:issued> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2012-08-21T13:09:14Z</dc:date> <dc:creator>Wittemann, Alexander</dc:creator> <dc:language>eng</dc:language> <dc:contributor>Jiménez, Maria Luisa</dc:contributor> <dcterms:abstract xml:lang="eng">We prcsent a study of the electrodynamic behavior of concentrated suspensions of spherical polyelectrolyte brushcs (SPBs). The dynamic mobility of the SPBs exhibits giant values. Concomitantly, . the dielectric spectra of suspensions of these particlcs display enormous loss peaks in the kHz frequency range. The strong dielectric relaxation is a direct consequence of the inhomogeneity of the counterion distribution inside the polyelectrolyte layer. As can be concluded from the experimentally determined relaxation frequency, the mobility of mono valent counterions is strongly diminished in the brush region. The dynamic behavior ofthe SPBs at high volume fractions can be explained by the assumption that the polyelectrolyte chains deform when particlcs approach each other.</dcterms:abstract> <dc:creator>Ahualli, Silvia</dc:creator> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/20181"/> <dc:contributor>Hoffmann, Marius</dc:contributor> <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/20181/1/wittemann_giant.pdf"/> <dc:contributor>Ballauff, Matthias</dc:contributor> <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/20181/1/wittemann_giant.pdf"/> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2012-08-21T13:09:14Z</dcterms:available> <dc:contributor>Delgado, Angel</dc:contributor> <dc:creator>Delgado, Angel</dc:creator> <dc:creator>Jiménez, Maria Luisa</dc:creator> <dcterms:bibliographicCitation>First publ. in: Soft Matter ; 8 (2011), 7. - pp. 3758-3762</dcterms:bibliographicCitation> <dc:contributor>Wittemann, Alexander</dc:contributor> <dcterms:rights rdf:resource="http://nbn-resolving.org/urn:nbn:de:bsz:352-20140905103605204-4002607-1"/> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> </rdf:Description> </rdf:RDF>

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