Synthesis of Diheteroarylamine Ligands by Palladium-Catalyzed Mono- and Diamination of Dichloroheteroarenes with Heteroarenamines
| Publikationstyp: | Zeitschriftenartikel |
| Autor/innen: | Samson, Daniel; Daltrozzo, Ewald |
| Erscheinungsjahr: | 2011 |
| Erschienen in: | Helvetica Chimica Acta ; 94 (2011), 1. - S. 46-60. - ISSN 0018-019X |
| DOI (zitierfähiger Link): | https://dx.doi.org/10.1002/hlca.201000148 |
| Zusammenfassung: |
The syntheses of bidentate (see 6 and 12), bis-bidentate (7, 10, and 13) up to oligo-bidentate (see 11 and 14) diheteroarylamine-based N,N-ligands are reported (Tables 2, 4, and 5). In the course of investigations on heteroaromatic (C[BOND]N)-bond formations, a protocol for the Pd-catalyzed mono- and diamination of 2,6-dichloropyridine (1) and 4,6-dichloropyrimidines 5 with heteroaren-2-amines 2 and pyrimidine-4,6-diamines 8 is developed. The results are applied to the syntheses of the ‘pentamers’ 11a–11d and the ‘heptamer’ 14 based on 4,6-disubstituted 2-alkylpyrimidines 5 and 8, respectively.
|
| Fachgebiet (DDC): | 540 Chemie |
| Schlagwörter: | diheteroarylamine ligands, diamination, amination, palladium catalysis, catalysis, heteroarenamines |
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SAMSON, Daniel, Ewald DALTROZZO, 2011. Synthesis of Diheteroarylamine Ligands by Palladium-Catalyzed Mono- and Diamination of Dichloroheteroarenes with Heteroarenamines. In: Helvetica Chimica Acta. 94(1), pp. 46-60. ISSN 0018-019X. Available under: doi: 10.1002/hlca.201000148
@article{Samson2011Synth-19307, title={Synthesis of Diheteroarylamine Ligands by Palladium-Catalyzed Mono- and Diamination of Dichloroheteroarenes with Heteroarenamines}, year={2011}, doi={10.1002/hlca.201000148}, number={1}, volume={94}, issn={0018-019X}, journal={Helvetica Chimica Acta}, pages={46--60}, author={Samson, Daniel and Daltrozzo, Ewald} }
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