Toward far-field vibrational spectroscopy of single molecules at room temperature

Winterhalder, Martin; Zumbusch, Andreas; Lippitz, Markus; Orrit, Michel

Toward far-field vibrational spectroscopy of single molecules at room temperature

Dateien

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Datum

2011

Autor:innen

Winterhalder, Martin

Zumbusch, Andreas

Lippitz, Markus

Orrit, Michel

Publikationstyp

Zeitschriftenartikel

Publikationsstatus

Published

Erschienen in

The Journal of Physical Chemistry B. 2011, 115(18), pp. 5425-5430. ISSN 1520-6106. eISSN 1520-5207. Available under: doi: 10.1021/jp109652s

Zusammenfassung

We propose a new scheme for the extraction of chemically sensitive vibrational information from a single fluorescent molecule at room temperature. Our approach is based on a three-photon fluorescence excitation scheme, with selectivity in the production of a vibrational population of the ground state. We estimate the expected signal in perturbation theory for a standard dye molecule, compare its magnitude qualitatively to noise and various background sources, and discuss the experimental realization of this scheme.

Fachgebiet (DDC)

540 Chemie

Zitieren

ISO 690

WINTERHALDER, Martin, Andreas ZUMBUSCH, Markus LIPPITZ, Michel ORRIT, 2011. Toward far-field vibrational spectroscopy of single molecules at room temperature. In: The Journal of Physical Chemistry B. 2011, 115(18), pp. 5425-5430. ISSN 1520-6106. eISSN 1520-5207. Available under: doi: 10.1021/jp109652s

BibTex

@article{Winterhalder2011-05-12Towar-19304,
  year={2011},
  doi={10.1021/jp109652s},
  title={Toward far-field vibrational spectroscopy of single molecules at room temperature},
  number={18},
  volume={115},
  issn={1520-6106},
  journal={The Journal of Physical Chemistry B},
  pages={5425--5430},
  author={Winterhalder, Martin and Zumbusch, Andreas and Lippitz, Markus and Orrit, Michel}
}

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