Synthesis of glycosylthiols and reactivity studies

Zitieren

Dateien zu dieser Ressource

Prüfsumme: MD5:1a263954b79dc1efbee86323d870dd26

DERE, Ravindra T., Amit KUMAR, Vipin KUMAR, Xiangming ZHU, Richard SCHMIDT, 2011. Synthesis of glycosylthiols and reactivity studies. In: The Journal of Organic Chemistry. 76(18), pp. 7539-7545. ISSN 0022-3263. eISSN 1520-6904. Available under: doi: 10.1021/jo200624e

@article{Dere2011-09-16Synth-18128, title={Synthesis of glycosylthiols and reactivity studies}, year={2011}, doi={10.1021/jo200624e}, number={18}, volume={76}, issn={0022-3263}, journal={The Journal of Organic Chemistry}, pages={7539--7545}, author={Dere, Ravindra T. and Kumar, Amit and Kumar, Vipin and Zhu, Xiangming and Schmidt, Richard} }

<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/18128"> <dc:creator>Kumar, Vipin</dc:creator> <dc:contributor>Schmidt, Richard</dc:contributor> <dc:creator>Dere, Ravindra T.</dc:creator> <dcterms:bibliographicCitation>First publ. in: Journal of Organic Chemistry ; 76 (2011), 18. - pp. 7539-7545</dcterms:bibliographicCitation> <dc:contributor>Kumar, Amit</dc:contributor> <dc:creator>Zhu, Xiangming</dc:creator> <dc:rights>deposit-license</dc:rights> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <foaf:homepage rdf:resource="http://localhost:8080/jspui"/> <dcterms:issued>2011-09-16</dcterms:issued> <dc:creator>Kumar, Amit</dc:creator> <dc:contributor>Kumar, Vipin</dc:contributor> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dc:language>eng</dc:language> <dc:contributor>Zhu, Xiangming</dc:contributor> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dc:creator>Schmidt, Richard</dc:creator> <dc:contributor>Dere, Ravindra T.</dc:contributor> <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/18128/1/Schmidt%20etal.pdf"/> <dcterms:abstract xml:lang="eng">The acid-catalyzed reaction of 1,2-anhydro-3,4,6-tri-Obenzyl- R-D-glucopyranose (7) as glycosyl donor with bis-trimethylsilyl sulfide as acceptor affords the R-thiol. Hence, this sterically hindered S-nucleophile as acceptor should provide with O-glycosyl trichloroacetimidates as glycosyl donors that have nonparticipating groups at C-2, glycosylthiols with the thiol group in axial position. This was confirmed for various donors (4, 16-19) with the exception of the corresponding mannosyl donor (20). However, powerful participating groups at C-2 of the donor (23-28) governed the anomeric selectivity.</dcterms:abstract> <dcterms:rights rdf:resource="http://nbn-resolving.org/urn:nbn:de:bsz:352-20140905103605204-4002607-1"/> <dcterms:title>Synthesis of glycosylthiols and reactivity studies</dcterms:title> <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/18128/1/Schmidt%20etal.pdf"/> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2012-06-30T22:25:08Z</dcterms:available> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2012-02-14T11:58:15Z</dc:date> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/18128"/> </rdf:Description> </rdf:RDF>

Dateiabrufe seit 01.10.2014 (Informationen über die Zugriffsstatistik)

Schmidt etal.pdf 129

Das Dokument erscheint in:

KOPS Suche


Stöbern

Mein Benutzerkonto