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Absolute configuration of volicitin, an elicitor of plant volatile biosynthesis from lepidopteran larvae

Absolute configuration of volicitin, an elicitor of plant volatile biosynthesis from lepidopteran larvae

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SPITELLER, Dieter, Georg POHNERT, Wilhelm BOLAND, 2001. Absolute configuration of volicitin, an elicitor of plant volatile biosynthesis from lepidopteran larvae. In: Tetrahedron Letters. 42(8), pp. 1483-1485. ISSN 0040-4039

@article{Spiteller2001Absol-15557, title={Absolute configuration of volicitin, an elicitor of plant volatile biosynthesis from lepidopteran larvae}, year={2001}, doi={10.1016/S0040-4039(00)02290-5}, number={8}, volume={42}, issn={0040-4039}, journal={Tetrahedron Letters}, pages={1483--1485}, author={Spiteller, Dieter and Pohnert, Georg and Boland, Wilhelm} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/15557"> <dcterms:title>Absolute configuration of volicitin, an elicitor of plant volatile biosynthesis from lepidopteran larvae</dcterms:title> <dc:rights>deposit-license</dc:rights> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-10-20T11:36:12Z</dc:date> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-10-20T11:36:12Z</dcterms:available> <dc:creator>Spiteller, Dieter</dc:creator> <dc:creator>Pohnert, Georg</dc:creator> <dc:contributor>Boland, Wilhelm</dc:contributor> <dcterms:abstract xml:lang="eng">The absolute configuration of the hydroxylinolenoyl moiety of volicitin (17-hydroxylinolenoyl-l-glutamine) 1a/b from four lepidopteran larvae was determined by methanolysis and derivatisation of the resulting ester with (1R)-1-phenyl-ethylisocyanate 3. The absolute configuration of the resulting (1′R)-17-(1′-phenyl-ethylcarbamoyloxy)-methyl linolenoates 4a/b followed from GLC comparison with synthetic references. Natural volicitin 1 from caterpillars of Spodoptera exigua, S. frugiperda, S. littoralis and Heliothis virescens (Noctuidae) exhibits a high ee (92–96%) and has a 17S configuration.</dcterms:abstract> <dc:contributor>Spiteller, Dieter</dc:contributor> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/15557"/> <dc:contributor>Pohnert, Georg</dc:contributor> <dc:creator>Boland, Wilhelm</dc:creator> <dcterms:rights rdf:resource="http://nbn-resolving.org/urn:nbn:de:bsz:352-20140905103605204-4002607-1"/> <dcterms:bibliographicCitation>Publ. in: Tetrahedron Letters ; 42 (2001), 8. - S. 1483-1485</dcterms:bibliographicCitation> <dc:language>eng</dc:language> <dcterms:issued>2001</dcterms:issued> </rdf:Description> </rdf:RDF>

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