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N-(15,16-Dihydroxylinoleoyl)-glutamine and N-(15,16-epoxylinoleoyl)-glutamine isolated from oral secretions of lepidopteran larvae

N-(15,16-Dihydroxylinoleoyl)-glutamine and N-(15,16-epoxylinoleoyl)-glutamine isolated from oral secretions of lepidopteran larvae

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SPITELLER, Dieter, Wilhelm BOLAND, 2003. N-(15,16-Dihydroxylinoleoyl)-glutamine and N-(15,16-epoxylinoleoyl)-glutamine isolated from oral secretions of lepidopteran larvae. In: Tetrahedron. 59(2), pp. 135-139. ISSN 0040-4020. Available under: doi: 10.1016/S0040-4020(02)01489-8

@article{Spiteller2003N1516-15552, title={N-(15,16-Dihydroxylinoleoyl)-glutamine and N-(15,16-epoxylinoleoyl)-glutamine isolated from oral secretions of lepidopteran larvae}, year={2003}, doi={10.1016/S0040-4020(02)01489-8}, number={2}, volume={59}, issn={0040-4020}, journal={Tetrahedron}, pages={135--139}, author={Spiteller, Dieter and Boland, Wilhelm} }

Boland, Wilhelm Spiteller, Dieter 2003 Publ. in: Tetrahedron ; 59 (2003), 2. - S. 135-139 terms-of-use 2011-10-20T11:44:30Z 2011-10-20T11:44:30Z Spiteller, Dieter Boland, Wilhelm eng N-(15,16-Dihydroxylinoleoyl)-glutamine (1) and N-(15,16-epoxylinoleoyl)-glutamine (2) and were identified in the regurgitant of lepidopteran larvae (Spodoptera exigua and Spodoptera frugiperda) by LC–MS. After methanolysis and derivatisation with MSTFA, the positions of the hydroxy groups of 1 were identified by GC–MS. The structures of both conjugates were confirmed by synthesis.<br /><br />The N-acyl glutamines 1 and 2 were isolated from the regurgitant of the lepidopteran larvae Spodoptera exigua and Spodoptera frugiperda. The structures were confirmed by synthesis. N-(15,16-Dihydroxylinoleoyl)-glutamine and N-(15,16-epoxylinoleoyl)-glutamine isolated from oral secretions of lepidopteran larvae

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