KOPS - Das Institutionelle Repositorium der Universität Konstanz

The Aza-Cope Rearrangement in Transition Metal Complexes. Construction of an Unsaturated C7-Ligand from Butadiyne and an Allylic Amine

The Aza-Cope Rearrangement in Transition Metal Complexes. Construction of an Unsaturated C7-Ligand from Butadiyne and an Allylic Amine

Zitieren

Dateien zu dieser Ressource

Prüfsumme: MD5:9d4cd9f928b19bc03cad8b52dd77b4ce

WINTER, Rainer, Fridmann HORNUNG, 1997. The Aza-Cope Rearrangement in Transition Metal Complexes. Construction of an Unsaturated C7-Ligand from Butadiyne and an Allylic Amine. In: Organometallics. 16(20), pp. 4248-4250. ISSN 0276-7333

@article{Winter1997Aza-C-13860, title={The Aza-Cope Rearrangement in Transition Metal Complexes. Construction of an Unsaturated C7-Ligand from Butadiyne and an Allylic Amine}, year={1997}, doi={10.1021/om9704511}, number={20}, volume={16}, issn={0276-7333}, journal={Organometallics}, pages={4248--4250}, author={Winter, Rainer and Hornung, Fridmann} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/13860"> <dcterms:bibliographicCitation>First publ. in: Organometallics 16 (1997), 20, pp. 4248-4250</dcterms:bibliographicCitation> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/13860"/> <dc:creator>Winter, Rainer</dc:creator> <dc:rights>deposit-license</dc:rights> <dcterms:title>The Aza-Cope Rearrangement in Transition Metal Complexes. Construction of an Unsaturated C7-Ligand from Butadiyne and an Allylic Amine</dcterms:title> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-06-28T08:54:01Z</dcterms:available> <dc:language>eng</dc:language> <dc:contributor>Winter, Rainer</dc:contributor> <dcterms:rights rdf:resource="http://nbn-resolving.org/urn:nbn:de:bsz:352-20140905103605204-4002607-1"/> <dcterms:issued>1997</dcterms:issued> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-06-28T08:54:01Z</dc:date> <dcterms:abstract xml:lang="eng">cis-RuCl2(L2)2 reacts with butadiyne in the presence of NaPF6 to give the butatrienylidene intermediate trans-[RuCl(L2)2CCCCH2]+, which can be trapped with tertiary amines to afford the ammoniobutenynyl complexes trans-[RuCl(L2)2CCC(NR3) CH2]+ (L2 = dppm; R = Et, Pr). The respective N-allyl derivatives trans-[RuCl(L2)2CCC((NMe2)allyl) CH2]+ (L = dppm, depe) rearrange under ambient conditions via an aza-Cope process to the amino-substituted allenylidene complexes trans-[RuCl(L2)2 CCC(NMe2)(CH2)2CHCH2]+.</dcterms:abstract> <dc:contributor>Hornung, Fridmann</dc:contributor> <dc:creator>Hornung, Fridmann</dc:creator> </rdf:Description> </rdf:RDF>

Dateiabrufe seit 01.10.2014 (Informationen über die Zugriffsstatistik)

winter_aza-cope.pdf 114

Das Dokument erscheint in:

KOPS Suche


Stöbern

Mein Benutzerkonto