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Synthesis, Structures, Ligand Substitution Reactions, and Electrochemistry of the Nitrile Complexes cis-[Ru(dppm)2Cl(NCR)]+ PF6– (dppm = Bis(diphenylphosphino)methane, R = CH3, C2H5, tBu, Ph)

Synthesis, Structures, Ligand Substitution Reactions, and Electrochemistry of the Nitrile Complexes cis-[Ru(dppm)2Cl(NCR)]+ PF6– (dppm = Bis(diphenylphosphino)methane, R = CH3, C2H5, tBu, Ph)

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WINTER, Rainer, Thomas SCHEIRING, 2000. Synthesis, Structures, Ligand Substitution Reactions, and Electrochemistry of the Nitrile Complexes cis-[Ru(dppm)2Cl(NCR)]+ PF6– (dppm = Bis(diphenylphosphino)methane, R = CH3, C2H5, tBu, Ph). In: Zeitschrift für anorganische und allgemeine Chemie. 626(5), pp. 1196-1204. ISSN 0044-2313

@article{Winter2000Synth-13855, title={Synthesis, Structures, Ligand Substitution Reactions, and Electrochemistry of the Nitrile Complexes cis-[Ru(dppm)2Cl(NCR)]+ PF6– (dppm = Bis(diphenylphosphino)methane, R = CH3, C2H5, tBu, Ph)}, year={2000}, doi={10.1002/(SICI)1521-3749(200005)626:5<1196::AID-ZAAC1196>3.0.CO;2-B}, number={5}, volume={626}, issn={0044-2313}, journal={Zeitschrift für anorganische und allgemeine Chemie}, pages={1196--1204}, author={Winter, Rainer and Scheiring, Thomas} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/13855"> <dc:language>eng</dc:language> <dc:creator>Winter, Rainer</dc:creator> <dcterms:abstract xml:lang="eng">Isomerically pure nitrile complexes cis-[Ru(dppm)2Cl(NCR)]+ (2 a–d) are formed upon chloride displacement from cis-[Ru(dppm)2Cl2] (1) or, alternatively, by ligand substitution from the acetonitrile complex 2 a. This latter approach does also allow for the introduction of pyridine (3 a,b), heptamethyldisilazane (4) or isonitrile ligands (5). All complexes are obtained as the configurationally stable cis-isomers. Only cis-[Ru(dppm)2Cl(CNtBu)]+ slowly isomerizes to the trans from. The solid state structures of the CH3CN, C2H5CN and the trans-tBuNC complexes were established by X-ray crystallography. Electrochemical investigations of the nitrile complexes 2 a–d show in addition to a chemically reversible one-electron oxidation an irrversible reduction step. In CH2Cl2 solution, cis- and trans-[Ru(dppm)2Cl2] have been identified as the final products of the electrochemically induced reaction sequence.</dcterms:abstract> <dc:rights>deposit-license</dc:rights> <dcterms:issued>2000</dcterms:issued> <dcterms:alternative>Synthese, Strukturen, Ligandenaustauschreaktionen und Elektrochemisches Verhalten der Nitrilkomplexe cis-[Ru(dppm)2Cl(NCR)]+ PF6– (dppm = Bis(diphenylphosphino)methan, R = CH3, C2H5, tBu, Ph)</dcterms:alternative> <dc:contributor>Scheiring, Thomas</dc:contributor> <dc:contributor>Winter, Rainer</dc:contributor> <dcterms:bibliographicCitation>First publ. in: Zeitschrift für anorganische und allgemeine Chemie 626 (2000), 5, pp. 1196–1204</dcterms:bibliographicCitation> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-06-27T13:59:51Z</dc:date> <dc:creator>Scheiring, Thomas</dc:creator> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-06-27T13:59:51Z</dcterms:available> <dcterms:title>Synthesis, Structures, Ligand Substitution Reactions, and Electrochemistry of the Nitrile Complexes cis-[Ru(dppm)2Cl(NCR)]+ PF6– (dppm = Bis(diphenylphosphino)methane, R = CH3, C2H5, tBu, Ph)</dcterms:title> <dcterms:rights rdf:resource="http://nbn-resolving.org/urn:nbn:de:bsz:352-20140905103605204-4002607-1"/> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/13855"/> </rdf:Description> </rdf:RDF>

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