Allenylidene complexes of ruthenium: synthesis, spectroscopy and electron transfer properties
| Type of Publication: | Journal article |
| Author: | Winter, Rainer; Zális, Stanislav |
| Year of publication: | 2004 |
| Published in: | Coordination Chemistry Reviews ; 248 (2004), 15-16. - pp. 1565-1583. - ISSN 0010-8545 |
| DOI (citable link): | https://dx.doi.org/10.1016/j.ccr.2004.05.005 |
| Summary: |
This contribution deals with cationic ruthenium allenylidene complexes bearing a large variety of differently substituted allenylidene ligands attached to the metal. We discuss their synthesis and how the identity of the ERn substituent influences their spectroscopic and electrochemical properties. It is shown, how data from different spectroscopies and electrochemical half-wave potentials relate to each others and provide a consistent picture of the bonding within these systems. Experimental results are compared to those from quantum mechanical studies.
Keywords: Allenylidene complexes of ruthenium; Spectroscopy; Electron transfer |
| Subject (DDC): | 540 Chemistry |
| Keywords: | Allenylidene complexes of ruthenium, Spectroscopy, Electron transfer |
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WINTER, Rainer, Stanislav ZÁLIS, 2004. Allenylidene complexes of ruthenium: synthesis, spectroscopy and electron transfer properties. In: Coordination Chemistry Reviews. 248(15-16), pp. 1565-1583. ISSN 0010-8545. Available under: doi: 10.1016/j.ccr.2004.05.005
@article{Winter2004Allen-13831, title={Allenylidene complexes of ruthenium: synthesis, spectroscopy and electron transfer properties}, year={2004}, doi={10.1016/j.ccr.2004.05.005}, number={15-16}, volume={248}, issn={0010-8545}, journal={Coordination Chemistry Reviews}, pages={1565--1583}, author={Winter, Rainer and Zális, Stanislav} }
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