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Allenylidene complexes of ruthenium: synthesis, spectroscopy and electron transfer properties

Allenylidene complexes of ruthenium: synthesis, spectroscopy and electron transfer properties

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WINTER, Rainer, Stanislav ZÁLIS, 2004. Allenylidene complexes of ruthenium: synthesis, spectroscopy and electron transfer properties. In: Coordination Chemistry Reviews. 248(15-16), pp. 1565-1583. ISSN 0010-8545. Available under: doi: 10.1016/j.ccr.2004.05.005

@article{Winter2004Allen-13831, title={Allenylidene complexes of ruthenium: synthesis, spectroscopy and electron transfer properties}, year={2004}, doi={10.1016/j.ccr.2004.05.005}, number={15-16}, volume={248}, issn={0010-8545}, journal={Coordination Chemistry Reviews}, pages={1565--1583}, author={Winter, Rainer and Zális, Stanislav} }

Zális, Stanislav eng This contribution deals with cationic ruthenium allenylidene complexes bearing a large variety of differently substituted allenylidene ligands attached to the metal. We discuss their synthesis and how the identity of the ERn substituent influences their spectroscopic and electrochemical properties. It is shown, how data from different spectroscopies and electrochemical half-wave potentials relate to each others and provide a consistent picture of the bonding within these systems. Experimental results are compared to those from quantum mechanical studies.<br /><br />Keywords: Allenylidene complexes of ruthenium; Spectroscopy; Electron transfer Allenylidene complexes of ruthenium: synthesis, spectroscopy and electron transfer properties Winter, Rainer Publ. in: Coordination Chemistry Reviews 248 (2004), 15-16, pp. 1565-1583 Winter, Rainer terms-of-use 2004 2011-06-27T11:38:43Z 2011-06-27T11:38:43Z Zális, Stanislav

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