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Synthesis of a Large Organometallic Macrocycle Comprising Four Ga−Ga Bonds and Four Bridging Ferrocene Dicarboxylato Ligands

Synthesis of a Large Organometallic Macrocycle Comprising Four Ga−Ga Bonds and Four Bridging Ferrocene Dicarboxylato Ligands

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UHL, Werner, Thomas SPIES, Detlev HAASE, Rainer WINTER, Wolfgang KAIM, 2000. Synthesis of a Large Organometallic Macrocycle Comprising Four Ga−Ga Bonds and Four Bridging Ferrocene Dicarboxylato Ligands. In: Organometallics. 19(6), pp. 1128-1131. ISSN 0276-7333

@article{Uhl2000Synth-13818, title={Synthesis of a Large Organometallic Macrocycle Comprising Four Ga−Ga Bonds and Four Bridging Ferrocene Dicarboxylato Ligands}, year={2000}, doi={10.1021/om990875q}, number={6}, volume={19}, issn={0276-7333}, journal={Organometallics}, pages={1128--1131}, author={Uhl, Werner and Spies, Thomas and Haase, Detlev and Winter, Rainer and Kaim, Wolfgang} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/13818"> <dc:rights>deposit-license</dc:rights> <dc:creator>Spies, Thomas</dc:creator> <dc:creator>Kaim, Wolfgang</dc:creator> <dc:contributor>Haase, Detlev</dc:contributor> <dcterms:bibliographicCitation>First publ. in: Organometallics 19 (2000), 6, pp. 1128-1131</dcterms:bibliographicCitation> <dcterms:issued>2000</dcterms:issued> <dc:contributor>Winter, Rainer</dc:contributor> <dc:contributor>Kaim, Wolfgang</dc:contributor> <dcterms:rights rdf:resource="http://nbn-resolving.org/urn:nbn:de:bsz:352-20140905103605204-4002607-1"/> <dc:creator>Winter, Rainer</dc:creator> <dc:contributor>Uhl, Werner</dc:contributor> <dcterms:abstract xml:lang="eng">The reaction of tetrakis[bis(trimethylsilyl)methyl]digallane(4), 1, with 1,1‘-ferrocenedicarboxylic acid afforded orange-red crystals of the macrocyclic compound 2 in a yield of 84%. 2 contains a large 32-atom heterocycle, which comprises four Ga−Ga single bonds bridged by four 1,1‘-ferrocenedicarboxylato ligands. The largest diameter of the molecule is about 2.5 nm. The redox-active Ga−Ga sites and ferrocene iron centers are all oxidized irreversibly within a narrow potential range.</dcterms:abstract> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-06-23T18:50:39Z</dcterms:available> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-06-23T18:50:39Z</dc:date> <dc:contributor>Spies, Thomas</dc:contributor> <dc:creator>Uhl, Werner</dc:creator> <dcterms:title>Synthesis of a Large Organometallic Macrocycle Comprising Four Ga−Ga Bonds and Four Bridging Ferrocene Dicarboxylato Ligands</dcterms:title> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/13818"/> <dc:language>eng</dc:language> <dc:creator>Haase, Detlev</dc:creator> </rdf:Description> </rdf:RDF>

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