Fullerene C60 as an Endohedral Molecule within an Inorganic Supramolecule

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SCHEER, Manfred, Andrea SCHINDLER, Roger MERKLE, Brian P. JOHNSON, Michael LINSEIS, Rainer WINTER, Christopher E. ANSON, Alexander V. VIROVETS, 2007. Fullerene C60 as an Endohedral Molecule within an Inorganic Supramolecule. In: Journal of the American Chemical Society. 129(44), pp. 13386-13387. ISSN 0002-7863

@article{Scheer2007-11-07Fulle-13798, title={Fullerene C60 as an Endohedral Molecule within an Inorganic Supramolecule}, year={2007}, doi={10.1021/ja075926m}, number={44}, volume={129}, issn={0002-7863}, journal={Journal of the American Chemical Society}, pages={13386--13387}, author={Scheer, Manfred and Schindler, Andrea and Merkle, Roger and Johnson, Brian P. and Linseis, Michael and Winter, Rainer and Anson, Christopher E. and Virovets, Alexander V.} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/13798"> <dc:contributor>Schindler, Andrea</dc:contributor> <dcterms:bibliographicCitation>First publ. in: Journal of the American Chemical Society 129 (2007), 44, pp. 13386–13387</dcterms:bibliographicCitation> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-06-22T09:16:47Z</dcterms:available> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/13798"/> <dc:creator>Merkle, Roger</dc:creator> <dc:contributor>Winter, Rainer</dc:contributor> <dc:creator>Linseis, Michael</dc:creator> <dc:contributor>Scheer, Manfred</dc:contributor> <dcterms:issued>2007-11-07</dcterms:issued> <dc:contributor>Johnson, Brian P.</dc:contributor> <dc:language>eng</dc:language> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-06-22T09:16:47Z</dc:date> <dc:creator>Anson, Christopher E.</dc:creator> <dc:contributor>Linseis, Michael</dc:contributor> <dc:contributor>Virovets, Alexander V.</dc:contributor> <dc:creator>Scheer, Manfred</dc:creator> <dcterms:title>Fullerene C60 as an Endohedral Molecule within an Inorganic Supramolecule</dcterms:title> <dcterms:abstract xml:lang="eng">C60[Cu26Cl26L2{Cp*Fe(η5-P5)}13(CH3CN)9] (L = H2O) represents a first example of a complete encapsulation of C60 itself by an inorganic fullerene-like system via molecular recognition of the five- and sixfold-symmetric structural motif of C60. The product exhibits an inorganic cover consisting of 99 inorganic core atoms from pentaphosphaferrocene and Cu(I) chloride building blocks. This is the first instance of a hollow structure that completely encapsulates C60. The overall spherical molecule possesses an outer diameter of 2.3 nm and shows a remarkable electronic interaction between C60 and the encapsulating giant molecule.</dcterms:abstract> <dc:rights>deposit-license</dc:rights> <dc:creator>Johnson, Brian P.</dc:creator> <dc:contributor>Anson, Christopher E.</dc:contributor> <dc:creator>Virovets, Alexander V.</dc:creator> <dc:contributor>Merkle, Roger</dc:contributor> <dc:creator>Schindler, Andrea</dc:creator> <dc:creator>Winter, Rainer</dc:creator> <dcterms:rights rdf:resource="http://nbn-resolving.org/urn:nbn:de:bsz:352-20140905103605204-4002607-1"/> </rdf:Description> </rdf:RDF>

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