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Highly Efficient Synthesis of (Phosphinodihydrooxazole)(1,5-cyclooctadiene) Iridium Complexes

Highly Efficient Synthesis of (Phosphinodihydrooxazole)(1,5-cyclooctadiene) Iridium Complexes

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SEMENIUCHENKO, Volodymyr, Volodymyr KHILYA, Ulrich GROTH, 2009. Highly Efficient Synthesis of (Phosphinodihydrooxazole)(1,5-cyclooctadiene) Iridium Complexes. In: Zeitschrift fur Naturforschung B: Journal of Chemical Sciences. 64b(10), pp. 1147-1158

@article{Semeniuchenko2009Highl-1033, title={Highly Efficient Synthesis of (Phosphinodihydrooxazole)(1,5-cyclooctadiene) Iridium Complexes}, year={2009}, number={10}, volume={64b}, journal={Zeitschrift fur Naturforschung B: Journal of Chemical Sciences}, pages={1147--1158}, author={Semeniuchenko, Volodymyr and Khilya, Volodymyr and Groth, Ulrich} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/1033"> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/1033"/> <dc:contributor>Groth, Ulrich</dc:contributor> <dcterms:issued>2009</dcterms:issued> <dc:creator>Khilya, Volodymyr</dc:creator> <dcterms:title>Highly Efficient Synthesis of (Phosphinodihydrooxazole)(1,5-cyclooctadiene) Iridium Complexes</dcterms:title> <dc:contributor>Khilya, Volodymyr</dc:contributor> <dcterms:bibliographicCitation>Publ. in: Zeitschrift fur Naturforschung B: Journal of Chemical Sciences 64b (2009), 10, pp. 1147-1158</dcterms:bibliographicCitation> <dc:language>eng</dc:language> <dcterms:rights rdf:resource="http://nbn-resolving.org/urn:nbn:de:bsz:352-20140905103416863-3868037-7"/> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-22T17:54:52Z</dcterms:available> <dc:creator>Semeniuchenko, Volodymyr</dc:creator> <dc:contributor>Semeniuchenko, Volodymyr</dc:contributor> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-22T17:54:52Z</dc:date> <dc:creator>Groth, Ulrich</dc:creator> <dc:rights>deposit-license</dc:rights> <dcterms:abstract xml:lang="eng">A highly efficient one-pot procedure for the synthesis of complexes of the type [Ir(COD)(Phox)]X, where Phox is a (chiral) phosphinooxazoline ligand, X = PF6 or B[(3,5-(CF3)2C6H3)]4 (BARF), is developed. Former reported syntheses demanded the isolation of pure ligands by column chromatography, but the ligands tend to adsorb irreversibly on silica. Moreover, the chromatography has to be performed with careful exclusion of air. The present method avoids this difficulties. The yields of the syntheses are comparable with those starting from the pure ligands. The method is also suitable for the preparation of complexes of the type [Rh(COD)(Phox)]BARF and [Rh(Phox)2]BARF.</dcterms:abstract> </rdf:Description> </rdf:RDF>

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