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Synthesis of (3S)-Hydroxyandrosta-5,7-diene-17-ones via Intramolecular Cobalt-Mediated [2+2+2] Cycloaddition

Synthesis of (3S)-Hydroxyandrosta-5,7-diene-17-ones via Intramolecular Cobalt-Mediated [2+2+2] Cycloaddition

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GROTH, Ulrich, Norbert RICHTER, Aris KALOGERAKIS, 2006. Synthesis of (3S)-Hydroxyandrosta-5,7-diene-17-ones via Intramolecular Cobalt-Mediated [2+2+2] Cycloaddition. In: Synlett. 2006(6), pp. 905-908. ISSN 0936-5214. eISSN 1437-2096

@article{Groth2006Synth-10068, title={Synthesis of (3S)-Hydroxyandrosta-5,7-diene-17-ones via Intramolecular Cobalt-Mediated [2+2+2] Cycloaddition}, year={2006}, doi={10.1055/s-2006-939064}, number={6}, volume={2006}, issn={0936-5214}, journal={Synlett}, pages={905--908}, author={Groth, Ulrich and Richter, Norbert and Kalogerakis, Aris} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/10068"> <dc:contributor>Kalogerakis, Aris</dc:contributor> <dcterms:bibliographicCitation>First publ. in: Synlett 2006, 6, pp. 905-908</dcterms:bibliographicCitation> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:16:22Z</dc:date> <dc:creator>Groth, Ulrich</dc:creator> <dc:format>application/pdf</dc:format> <dcterms:rights rdf:resource="https://creativecommons.org/licenses/by-nc-nd/2.0/legalcode"/> <dc:creator>Richter, Norbert</dc:creator> <dc:rights>deposit-license</dc:rights> <dc:creator>Kalogerakis, Aris</dc:creator> <dc:language>eng</dc:language> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:16:22Z</dcterms:available> <dcterms:issued>2006</dcterms:issued> <dcterms:title>Synthesis of (3S)-Hydroxyandrosta-5,7-diene-17-ones via Intramolecular Cobalt-Mediated [2+2+2] Cycloaddition</dcterms:title> <dc:contributor>Richter, Norbert</dc:contributor> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/10068"/> <dc:contributor>Groth, Ulrich</dc:contributor> <dcterms:abstract xml:lang="eng">A new method for the synthesis of lumisterin-type steroids following the D→ABCD approach is reported. A key step is the cobalt-induced cyclization of a cyclopentanoid enediyne, which was prepared via thioalkylation of the zinc enolate of a 2,3-substituted cyclopentanone with α-chlorosulfides.</dcterms:abstract> </rdf:Description> </rdf:RDF>

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