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Thio- and seleno-acrylamide derivatives from ynamines and transition metal-co-ordinated thio- and seleno-aldehydes and -ketones

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1987

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Tiriliomis, Athanassios
Gerbing, Ulrike
Huber, Brigitte

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http://nbn-resolving.de/urn:nbn:de:bsz:352-236886
DOI (zitierfähiger Link)
https://doi.org/10.1039/C39870000559
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Journal of the Chemical Society, Chemical Communications. 1987(8), pp. 559-560. ISSN 0022-4936. Available under: doi: 10.1039/C39870000559

Zusammenfassung

Pentacarbonyl-chromium- and -tungsten-co-ordinated thio- and seleno-aldehydes and selenoketones, respectively, react with 1-diethylaminoprop-1-yne via regiospecific [2 + 2] cycloaddition and stereospecific electrocyclic ring-opening to give metal-co-ordinated thio- and seleno-acrylamide derivatives which can be cleaved almost quantitatively from the metal by CO (100 atm.).

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540 Chemie

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ISO 690FISCHER, Helmut, Athanassios TIRILIOMIS, Ulrike GERBING, Brigitte HUBER, Gerhard MÜLLER, 1987. Thio- and seleno-acrylamide derivatives from ynamines and transition metal-co-ordinated thio- and seleno-aldehydes and -ketones. In: Journal of the Chemical Society, Chemical Communications. 1987(8), pp. 559-560. ISSN 0022-4936. Available under: doi: 10.1039/C39870000559
BibTex
@article{Fischer1987selen-23688,
  year={1987},
  doi={10.1039/C39870000559},
  title={Thio- and seleno-acrylamide derivatives from ynamines and transition metal-co-ordinated thio- and seleno-aldehydes and -ketones},
  number={8},
  issn={0022-4936},
  journal={Journal of the Chemical Society, Chemical Communications},
  pages={559--560},
  author={Fischer, Helmut and Tiriliomis, Athanassios and Gerbing, Ulrike and Huber, Brigitte and Müller, Gerhard}
}
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