Publikation: Formal total synthesis of (±)-strictamine – the [2,3]-Stevens rearrangement for construction of octahydro-2H-2,8-methanoquinolizines
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Chemical Communications : ChemComm. 2016, 52(76), pp. 11363-11365. ISSN 0009-241X. eISSN 1364-548X. Available under: doi: 10.1039/c6cc06125g
Zusammenfassung
For decades, akuammiline alkaloids have attracted synthetic chemists due to their intriguing molecular architecture. Among the different structural elements embedded in their carboskeleton, the methanoquinolizidine system constitutes the signature structural element of this alkaloid family. Herein, we describe a novel synthetic access to this system which relies on a [2,3]-Stevens rearrangement and results in the formal synthesis of strictamine.
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ECKERMANN, Ruben, Michael BREUNIG, Tanja GAICH, 2016. Formal total synthesis of (±)-strictamine – the [2,3]-Stevens rearrangement for construction of octahydro-2H-2,8-methanoquinolizines. In: Chemical Communications : ChemComm. 2016, 52(76), pp. 11363-11365. ISSN 0009-241X. eISSN 1364-548X. Available under: doi: 10.1039/c6cc06125gBibTex
@article{Eckermann2016Forma-37437,
year={2016},
doi={10.1039/c6cc06125g},
title={Formal total synthesis of (±)-strictamine – the [2,3]-Stevens rearrangement for construction of octahydro-2H-2,8-methanoquinolizines},
number={76},
volume={52},
issn={0009-241X},
journal={Chemical Communications : ChemComm},
pages={11363--11365},
author={Eckermann, Ruben and Breunig, Michael and Gaich, Tanja}
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