Publikation: Structure-activity and structure-selectivity correlations in metallocene-based catalysts for Alpha-olefin polymerization
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1993
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Makromolekulare Chemie. Macromolecular Symposia. 1993, 66(1), pp. 127-140. ISSN 0258-0322. eISSN 1521-3900. Available under: doi: 10.1002/masy.19930660113
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Zirconocene complexes carrying substituents at various positions of their ring-bridged ligand frameworks were studied as catalysts for methylalumoxane-activated propene polymerization. Effects of different substitution patterns on catalyst activities and on chain lengths and stereo- and regio-regularities of the polymers produced are correlated with geometrical features of the complexes, e.g. with parameters describing their structural rigidity or the aperture and obliquity of their coordination gaps.
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540 Chemie
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BURGER, Peter, Kai HORTMANN, Hans-Herbert BRINTZINGER, 1993. Structure-activity and structure-selectivity correlations in metallocene-based catalysts for Alpha-olefin polymerization. In: Makromolekulare Chemie. Macromolecular Symposia. 1993, 66(1), pp. 127-140. ISSN 0258-0322. eISSN 1521-3900. Available under: doi: 10.1002/masy.19930660113BibTex
@article{Burger1993Struc-24061, year={1993}, doi={10.1002/masy.19930660113}, title={Structure-activity and structure-selectivity correlations in metallocene-based catalysts for Alpha-olefin polymerization}, number={1}, volume={66}, issn={0258-0322}, journal={Makromolekulare Chemie. Macromolecular Symposia}, pages={127--140}, author={Burger, Peter and Hortmann, Kai and Brintzinger, Hans-Herbert} }
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