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Structure-activity and structure-selectivity correlations in metallocene-based catalysts for Alpha-olefin polymerization

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1993

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Makromolekulare Chemie. Macromolecular Symposia. 1993, 66(1), pp. 127-140. ISSN 0258-0322. eISSN 1521-3900. Available under: doi: 10.1002/masy.19930660113

Zusammenfassung

Zirconocene complexes carrying substituents at various positions of their ring-bridged ligand frameworks were studied as catalysts for methylalumoxane-activated propene polymerization. Effects of different substitution patterns on catalyst activities and on chain lengths and stereo- and regio-regularities of the polymers produced are correlated with geometrical features of the complexes, e.g. with parameters describing their structural rigidity or the aperture and obliquity of their coordination gaps.

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540 Chemie

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ISO 690BURGER, Peter, Kai HORTMANN, Hans-Herbert BRINTZINGER, 1993. Structure-activity and structure-selectivity correlations in metallocene-based catalysts for Alpha-olefin polymerization. In: Makromolekulare Chemie. Macromolecular Symposia. 1993, 66(1), pp. 127-140. ISSN 0258-0322. eISSN 1521-3900. Available under: doi: 10.1002/masy.19930660113
BibTex
@article{Burger1993Struc-24061,
  year={1993},
  doi={10.1002/masy.19930660113},
  title={Structure-activity and structure-selectivity correlations in metallocene-based catalysts for Alpha-olefin polymerization},
  number={1},
  volume={66},
  issn={0258-0322},
  journal={Makromolekulare Chemie. Macromolecular Symposia},
  pages={127--140},
  author={Burger, Peter and Hortmann, Kai and Brintzinger, Hans-Herbert}
}
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