Publikation:

Dimethyl titanocene Y : a valuable precursor for libraries of cytotoxic titanocene derivatives

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20_J.Inorg.Biochem.2010.pdf
20_J.Inorg.Biochem.2010.pdfGröße: 1.66 MBDownloads: 551

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2010

Autor:innen

Dürr, Christoph J.

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http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-130230
DOI (zitierfähiger Link)
https://doi.org/10.1016/j.jinorgbio.2010.04.003
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Chemie: Publikationen
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Published

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Journal of inorganic biochemistry. 2010, 104(8), pp. 863-867. ISSN 0162-0134. eISSN 1873-3344. Available under: doi: 10.1016/j.jinorgbio.2010.04.003

Zusammenfassung

Reaction of the known titanocene Y 2 with methyl lithium at -15 °C yields bis-[(p-methoxybenzyl)cyclopentadienyl]titanium(IV) dimethyl (dimethyl titanocene Y, 3), a hitherto unknown, surprisingly robust titanium (IV) dimethyl species. Dimethyl titanocene Y was utilized in the preparation of several bis-[(p-methoxybenzyl)cyclopentadienyl]titanium(IV) dicarboxylates by the reaction with the free carboxylic acids in fair to good yields. Cytotoxicity of all new compounds has been estimated in Hela S3 cells.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
540 Chemie

Schlagwörter

Cytotoxicity, Titanium complexes, Library-synthesis, Cancer

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ISO 690IMMEL, Timo, Josefine MARTIN, Christoph J. DÜRR, Ulrich GROTH, Thomas HUHN, 2010. Dimethyl titanocene Y : a valuable precursor for libraries of cytotoxic titanocene derivatives. In: Journal of inorganic biochemistry. 2010, 104(8), pp. 863-867. ISSN 0162-0134. eISSN 1873-3344. Available under: doi: 10.1016/j.jinorgbio.2010.04.003
BibTex
@article{Immel2010Dimet-10055,
  year={2010},
  doi={10.1016/j.jinorgbio.2010.04.003},
  title={Dimethyl titanocene Y : a valuable precursor for libraries of cytotoxic titanocene derivatives},
  number={8},
  volume={104},
  issn={0162-0134},
  journal={Journal of inorganic biochemistry},
  pages={863--867},
  author={Immel, Timo and Martin, Josefine and Dürr, Christoph J. and Groth, Ulrich and Huhn, Thomas}
}
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