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Pyrrolopyrrole cyanines : Effect of substituents on optical properties

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2011

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European Journal of Organic Chemistry. 2011, 2011(19), pp. 3421-3429. ISSN 1434-193X. Available under: doi: 10.1002/ejoc.201100108

Zusammenfassung

To tune their optical properties, a large variety of pyrrolopyrrole cyanines (PPCys) were synthesized with substitutedheteroaromatics such as quinoline, benzothiazole, and oxazole derivatives as terminal groups. Thus, a broad range of stable, highly fluorescing near-infrared (NIR) dyes with high absorptivities between 690 to 845 nm is accessible. The large number of newly synthesized compounds allows a detailed discussion of the correlation between molecular structure and the optical properties of the first electronic transition.

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540 Chemie

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chromophores, dyes/pigments, fluorescence, heterocycles, near-infrared dyes

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ISO 690FISCHER, Georg, Matthias KLEIN, Ewald DALTROZZO, Andreas ZUMBUSCH, 2011. Pyrrolopyrrole cyanines : Effect of substituents on optical properties. In: European Journal of Organic Chemistry. 2011, 2011(19), pp. 3421-3429. ISSN 1434-193X. Available under: doi: 10.1002/ejoc.201100108
BibTex
@article{Fischer2011Pyrro-19286,
  year={2011},
  doi={10.1002/ejoc.201100108},
  title={Pyrrolopyrrole cyanines : Effect of substituents on optical properties},
  number={19},
  volume={2011},
  issn={1434-193X},
  journal={European Journal of Organic Chemistry},
  pages={3421--3429},
  author={Fischer, Georg and Klein, Matthias and Daltrozzo, Ewald and Zumbusch, Andreas}
}
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    <dcterms:abstract xml:lang="eng">To tune their optical properties, a large variety of pyrrolopyrrole cyanines (PPCys) were synthesized with substitutedheteroaromatics such as quinoline, benzothiazole, and oxazole derivatives as terminal groups. Thus, a broad range of stable, highly fluorescing near-infrared (NIR) dyes with high absorptivities between 690 to 845 nm is accessible. The large number of newly synthesized compounds allows a detailed discussion of the correlation between molecular structure and the optical properties of the first electronic transition.</dcterms:abstract>
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