Azacyanines of the Pyrrolopyrrole Series

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2014
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Chemistry : A European Journal. 2014, 20(21), pp. 6494-6504. ISSN 0947-6539. eISSN 1521-3765. Available under: doi: 10.1002/chem.201304235
Zusammenfassung

reaction of POCl3-activated, readily soluble diketopyrrolopyrrole (DPP) with 2-aminoheteroaromatics to yield 1:1 and 1:2 hydrogen chelates is described. Complexation of these hydrogen chelates with boron reagents results in thermally and photochemically stable fluorescent dyes (PP–azacyanines). The 1:2 complexes in particular absorb at long wavelengths and are brightly fluorescing. The rich photophysics of the new compounds are presented. Both the pronounced vibrational fine structure of the S0[RIGHTWARDS ARROW]S1 transitions and the observed fluorescence phenomena allow detailed conclusions to be made on the correlation between molecular structure and optical properties

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540 Chemie
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absorption; chromophores; dyes/pigments; fluorescence; photophysics
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ISO 690MARKS, Timo, Ewald DALTROZZO, Andreas ZUMBUSCH, 2014. Azacyanines of the Pyrrolopyrrole Series. In: Chemistry : A European Journal. 2014, 20(21), pp. 6494-6504. ISSN 0947-6539. eISSN 1521-3765. Available under: doi: 10.1002/chem.201304235
BibTex
@article{Marks2014Azacy-29766,
  year={2014},
  doi={10.1002/chem.201304235},
  title={Azacyanines of the Pyrrolopyrrole Series},
  url={http://onlinelibrary.wiley.com/doi/10.1002/chem.201304235/abstract},
  number={21},
  volume={20},
  issn={0947-6539},
  journal={Chemistry : A European Journal},
  pages={6494--6504},
  author={Marks, Timo and Daltrozzo, Ewald and Zumbusch, Andreas}
}
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