Publikation: Stereochemistry of the Conversion of 2-Phenoxyethanol into Phenol and Acetaldehyde by Acetobacterium sp.
Lade...
Dateien
Datum
2003
Autor:innen
Herausgeber:innen
ISSN der Zeitschrift
Electronic ISSN
ISBN
Bibliografische Daten
Verlag
Schriftenreihe
Auflagebezeichnung
URI (zitierfähiger Link)
DOI (zitierfähiger Link)
Internationale Patentnummer
Link zur Lizenz
Angaben zur Forschungsförderung
Projekt
Open Access-Veröffentlichung
Open Access Green
Sammlungen
Core Facility der Universität Konstanz
Titel in einer weiteren Sprache
Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published
Erschienen in
Helvetica Chimica Acta. 2003, 86(7), pp. 2629-2636. ISSN 0018-019X. eISSN 1522-2675. Available under: doi: 10.1002/hlca.200390212
Zusammenfassung
The conversion of 2-phenoxyethanol to phenol and acetate by the anaerobic bacterium Acetobacterium sp. strain LuPhet1 proceeds through acetaldehyde with concomitant migration of a H-atom from C(1) to C(2) of the glycolic moiety. Separate feeding experiments with (R)- and (S)-2-phenoxy(1-2H)ethanol, prepared via chemoenzymatic syntheses, indicate that the H-atom involved in the 1,2-shift is the pro-S one of the enantiotopic couple of the alcohol function.
Zusammenfassung in einer weiteren Sprache
Fachgebiet (DDC)
570 Biowissenschaften, Biologie
Schlagwörter
Konferenz
Rezension
undefined / . - undefined, undefined
Zitieren
ISO 690
SPERANZA, Giovanna, Britta MÜLLER, Maximilian ORLANDI, Carlo F. MORELLI, Paolo MANITTO, Bernhard SCHINK, 2003. Stereochemistry of the Conversion of 2-Phenoxyethanol into Phenol and Acetaldehyde by Acetobacterium sp.. In: Helvetica Chimica Acta. 2003, 86(7), pp. 2629-2636. ISSN 0018-019X. eISSN 1522-2675. Available under: doi: 10.1002/hlca.200390212BibTex
@article{Speranza2003Stere-7648,
year={2003},
doi={10.1002/hlca.200390212},
title={Stereochemistry of the Conversion of 2-Phenoxyethanol into Phenol and Acetaldehyde by Acetobacterium sp.},
number={7},
volume={86},
issn={0018-019X},
journal={Helvetica Chimica Acta},
pages={2629--2636},
author={Speranza, Giovanna and Müller, Britta and Orlandi, Maximilian and Morelli, Carlo F. and Manitto, Paolo and Schink, Bernhard}
}RDF
<rdf:RDF
xmlns:dcterms="http://purl.org/dc/terms/"
xmlns:dc="http://purl.org/dc/elements/1.1/"
xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
xmlns:bibo="http://purl.org/ontology/bibo/"
xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
xmlns:foaf="http://xmlns.com/foaf/0.1/"
xmlns:void="http://rdfs.org/ns/void#"
xmlns:xsd="http://www.w3.org/2001/XMLSchema#" >
<rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/7648">
<dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/7648/1/stereochemistry_2003.pdf"/>
<dc:contributor>Morelli, Carlo F.</dc:contributor>
<dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/7648/1/stereochemistry_2003.pdf"/>
<bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/7648"/>
<dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/28"/>
<dc:creator>Speranza, Giovanna</dc:creator>
<dcterms:issued>2003</dcterms:issued>
<dc:creator>Morelli, Carlo F.</dc:creator>
<dcterms:bibliographicCitation>First publ. in: Helvetica Chimica Acta 86 (2003), 7, pp. 2629-2636</dcterms:bibliographicCitation>
<dc:creator>Schink, Bernhard</dc:creator>
<dc:creator>Orlandi, Maximilian</dc:creator>
<dc:creator>Müller, Britta</dc:creator>
<dc:contributor>Müller, Britta</dc:contributor>
<dcterms:rights rdf:resource="http://creativecommons.org/licenses/by-nc-nd/2.0/"/>
<void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
<dcterms:abstract xml:lang="eng">The conversion of 2-phenoxyethanol to phenol and acetate by the anaerobic bacterium Acetobacterium sp. strain LuPhet1 proceeds through acetaldehyde with concomitant migration of a H-atom from C(1) to C(2) of the glycolic moiety. Separate feeding experiments with (R)- and (S)-2-phenoxy(1-2H)ethanol, prepared via chemoenzymatic syntheses, indicate that the H-atom involved in the 1,2-shift is the pro-S one of the enantiotopic couple of the alcohol function.</dcterms:abstract>
<dc:format>application/pdf</dc:format>
<dcterms:title>Stereochemistry of the Conversion of 2-Phenoxyethanol into Phenol and Acetaldehyde by Acetobacterium sp.</dcterms:title>
<dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/28"/>
<foaf:homepage rdf:resource="http://localhost:8080/"/>
<dc:contributor>Speranza, Giovanna</dc:contributor>
<dc:contributor>Orlandi, Maximilian</dc:contributor>
<dc:language>eng</dc:language>
<dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T17:36:03Z</dc:date>
<dc:contributor>Manitto, Paolo</dc:contributor>
<dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T17:36:03Z</dcterms:available>
<dc:rights>Attribution-NonCommercial-NoDerivs 2.0 Generic</dc:rights>
<dc:creator>Manitto, Paolo</dc:creator>
<dc:contributor>Schink, Bernhard</dc:contributor>
</rdf:Description>
</rdf:RDF>Interner Vermerk
xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter
Prüfungsdatum der Dissertation
Finanzierungsart
Kommentar zur Publikation
Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Ja
