Publikation:

Extremely Narrow-Dispersed High Molecular Weight Polyethylene from Living Polymerization at Elevated Temperatures with o-F Substituted Ti Enolatoimines

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2008_JACS_130_13204_Yu_Mecking_narrow_dispersity_PE.pdf
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2008

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Yu, Sze-Man

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http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-73554
DOI (zitierfähiger Link)
https://doi.org/10.1021/ja805304p
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Attribution-NonCommercial-NoDerivs 2.0 Generic

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Open Access Green

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Chemie: Publikationen
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Published

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Journal of the American Chemical Society. 2008, 130(40), pp. 13204-13205. ISSN 0002-7863. eISSN 1520-5126. Available under: doi: 10.1021/ja805304p

Zusammenfassung

With a new titanium imineenolato complex, ethylene is polymerized in an unprecedented living fashion affording a polymer with a high molecular weight (Mn > 105 g mol−1) and an extremely narrow distribution (Mw/Mn 1.01) at the same time; the living character is also retained even at an elevated temperature of 75 °C, and blockcopolymers are accessible.

Zusammenfassung in einer weiteren Sprache

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540 Chemie

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ISO 690YU, Sze-Man, Stefan MECKING, 2008. Extremely Narrow-Dispersed High Molecular Weight Polyethylene from Living Polymerization at Elevated Temperatures with o-F Substituted Ti Enolatoimines. In: Journal of the American Chemical Society. 2008, 130(40), pp. 13204-13205. ISSN 0002-7863. eISSN 1520-5126. Available under: doi: 10.1021/ja805304p
BibTex
@article{Yu2008Extre-9869,
  year={2008},
  doi={10.1021/ja805304p},
  title={Extremely Narrow-Dispersed High Molecular Weight Polyethylene from Living Polymerization at Elevated Temperatures with o-F Substituted Ti Enolatoimines},
  number={40},
  volume={130},
  issn={0002-7863},
  journal={Journal of the American Chemical Society},
  pages={13204--13205},
  author={Yu, Sze-Man and Mecking, Stefan}
}
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