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Transition Metal Heteroaldehyde and Heteroketone Complexes

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1999

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Stumpf, Rüdiger
Roth, Gerhard

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Advances in Organometallic Chemistry

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Journal of Algebra 304 (2006) 216-236. Elsevier, pp. 125-196. Advances in Organometallic Chemistry. 43. ISSN 0065-3055. ISBN 978-0-12-031143-9. Available under: doi: 10.1016/S0065-3055(08)60670-X

Zusammenfassung

This chapter discusses transition metal heteroaldehyde and heteroketone complexes. The chapter includes a discussion on the synthesis and properties of chalcogenoaldehyde and -ketone complexes. The coverage is essentially limited to mono- and binuclear complexes with R1 (R2) C = E ligands (R1, R2 = H, alkyl, aryl, and alkenyl). The chapter describes the stabilization of the heteroaldehydes and -ketones by coordination to transition metals. These heteroaldehydes and heteroketones are generated in solution in the presence of suitable substrates, and are immediately trapped. It also highlights the synthesis, properties, and reactivity of thioaldehydes and thioketones. Many problems connected with the high reactivity of these heterocarbonyl compounds can be circumvented, using their transition metal complexes. The chemistry of organosulfur and organoselenium transition metal complexes and aspects of the thio- and selenoaldehydes and -ketones as ligands have been discusses in the chapter.

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540 Chemie

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ISO 690FISCHER, Helmut, Rüdiger STUMPF, Gerhard ROTH, 1999. Transition Metal Heteroaldehyde and Heteroketone Complexes. In: Journal of Algebra 304 (2006) 216-236. Elsevier, pp. 125-196. Advances in Organometallic Chemistry. 43. ISSN 0065-3055. ISBN 978-0-12-031143-9. Available under: doi: 10.1016/S0065-3055(08)60670-X
BibTex
@article{Fischer1999Trans-23046,
  year={1999},
  doi={10.1016/S0065-3055(08)60670-X},
  title={Transition Metal Heteroaldehyde and Heteroketone Complexes},
  issn={0065-3055},
  journal={Journal of Algebra 304 (2006) 216-236},
  pages={125--196},
  author={Fischer, Helmut and Stumpf, Rüdiger and Roth, Gerhard},
  note={Latex, 12 pages, acknowledgment added}
}
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Latex, 12 pages, acknowledgment added
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