Synergetic Effect of Monomer Functional Group Coordination in Catalytic Insertion Polymerization

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dc.contributor.authorLeicht, Hannes
dc.contributor.authorGöttker-Schnetmann, Inigo
dc.contributor.authorMecking, Stefan
dc.date.accessioned2017-06-01T09:50:23Z
dc.date.available2017-06-01T09:50:23Z
dc.date.issued2017-05-24eng
dc.description.abstractPhS- and PhNH-functionalized dienes are copolymerized efficiently with butadiene to stereoregular copolymers by [(mesitylene)Ni(allyl)][BAr(F)4] (Ni-1). Overall polymerization rates and comonomer incorporations depend strongly on the linker length between the diene moiety and functional group, in, e.g., PhS-(CH2)xC(═CH2)-CH═CH2 (PhS-x-BD, x = 3-7), in particular for certain linker lengths high comonomer reactivity ratios stand out. This effect is related to a favorable binding of the comonomer to the active site comprising coordination of its functional group, which significantly enhances comonomer incorporation in the growing polymer chain.eng
dc.description.versionpublishedeng
dc.identifier.doi10.1021/jacs.7b03087eng
dc.identifier.pmid28504883eng
dc.identifier.urihttps://kops.uni-konstanz.de/handle/123456789/39106
dc.language.isoengeng
dc.subject.ddc540eng
dc.titleSynergetic Effect of Monomer Functional Group Coordination in Catalytic Insertion Polymerizationeng
dc.typeJOURNAL_ARTICLEeng
dspace.entity.typePublication
kops.citation.bibtex
@article{Leicht2017-05-24Syner-39106,
  year={2017},
  doi={10.1021/jacs.7b03087},
  title={Synergetic Effect of Monomer Functional Group Coordination in Catalytic Insertion Polymerization},
  number={20},
  volume={139},
  issn={0002-7863},
  journal={Journal of the American Chemical Society : JACS},
  pages={6823--6826},
  author={Leicht, Hannes and Göttker-Schnetmann, Inigo and Mecking, Stefan}
}
kops.citation.iso690LEICHT, Hannes, Inigo GÖTTKER-SCHNETMANN, Stefan MECKING, 2017. Synergetic Effect of Monomer Functional Group Coordination in Catalytic Insertion Polymerization. In: Journal of the American Chemical Society : JACS. 2017, 139(20), pp. 6823-6826. ISSN 0002-7863. eISSN 1520-5126. Available under: doi: 10.1021/jacs.7b03087deu
kops.citation.iso690LEICHT, Hannes, Inigo GÖTTKER-SCHNETMANN, Stefan MECKING, 2017. Synergetic Effect of Monomer Functional Group Coordination in Catalytic Insertion Polymerization. In: Journal of the American Chemical Society : JACS. 2017, 139(20), pp. 6823-6826. ISSN 0002-7863. eISSN 1520-5126. Available under: doi: 10.1021/jacs.7b03087eng
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    <dcterms:abstract xml:lang="eng">PhS- and PhNH-functionalized dienes are copolymerized efficiently with butadiene to stereoregular copolymers by [(mesitylene)Ni(allyl)][BAr(F)4] (Ni-1). Overall polymerization rates and comonomer incorporations depend strongly on the linker length between the diene moiety and functional group, in, e.g., PhS-(CH2)xC(═CH2)-CH═CH2 (PhS-x-BD, x = 3-7), in particular for certain linker lengths high comonomer reactivity ratios stand out. This effect is related to a favorable binding of the comonomer to the active site comprising coordination of its functional group, which significantly enhances comonomer incorporation in the growing polymer chain.</dcterms:abstract>
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kops.sourcefieldJournal of the American Chemical Society : JACS. 2017, <b>139</b>(20), pp. 6823-6826. ISSN 0002-7863. eISSN 1520-5126. Available under: doi: 10.1021/jacs.7b03087deu
kops.sourcefield.plainJournal of the American Chemical Society : JACS. 2017, 139(20), pp. 6823-6826. ISSN 0002-7863. eISSN 1520-5126. Available under: doi: 10.1021/jacs.7b03087deu
kops.sourcefield.plainJournal of the American Chemical Society : JACS. 2017, 139(20), pp. 6823-6826. ISSN 0002-7863. eISSN 1520-5126. Available under: doi: 10.1021/jacs.7b03087eng
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