Publikation: Unexpected migration of the indenyl ligand in the reaction of alkynyl(η5-indenyl)iron complexes with phosphanes and phosphites from iron to the alkynyl group
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1999
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Scheck, Peter
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Chemical Communications. 1999(11), pp. 1031-1032. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/A902785H
Zusammenfassung
Novel indenylvinylidene iron complexes are formed in the reaction of alkynyl(η5-indenyl)iron complexes with phosphites and phosphanes in large excess by an intermolecular transfer of the indenyl ligand from iron to the Cβ atom of the alkynyl ligand; mechanistic studies indicate that the reaction proceeds by a radical pathway.
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540 Chemie
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FISCHER, Helmut, Peter SCHECK, 1999. Unexpected migration of the indenyl ligand in the reaction of alkynyl(η5-indenyl)iron complexes with phosphanes and phosphites from iron to the alkynyl group. In: Chemical Communications. 1999(11), pp. 1031-1032. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/A902785HBibTex
@article{Fischer1999Unexp-23037, year={1999}, doi={10.1039/A902785H}, title={Unexpected migration of the indenyl ligand in the reaction of alkynyl(η5-indenyl)iron complexes with phosphanes and phosphites from iron to the alkynyl group}, number={11}, issn={1359-7345}, journal={Chemical Communications}, pages={1031--1032}, author={Fischer, Helmut and Scheck, Peter} }
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