Manipulating π-π Interactions between Single Molecules by Using Antenna Electrodes as Optical Tweezers

Kurzanzeige
dc.contributor.authorXu, Xiaona
dc.contributor.authorQi, Qiang
dc.contributor.authorHu, Qihong
dc.contributor.authorMa, Liang
dc.contributor.authorEmusani, Ramya
dc.contributor.authorZhang, Surong
dc.contributor.authorZhao, Xueyan
dc.contributor.authorTan, Min
dc.contributor.authorAdijiang, Adila
dc.contributor.authorZhang, Wei
dc.contributor.authorMa, Ziwei
dc.contributor.authorTian, Guangjun
dc.contributor.authorScheer, Elke
dc.contributor.authorXiang, Dong
dc.date.accessioned2025-01-14T13:55:21Z
dc.date.available2025-01-14T13:55:21Z
dc.date.issued2024-12-02
dc.description.abstractVia conductance measurements of thousands of single-molecule junctions, we report that the 𝜋–𝜋 coupling between neighboring aromatic molecules can be manipulated by laser illumination. We reveal that this optical manipulation originates from the optical plasmonic gradient force generated inside the nanogaps, in which the gapped antenna electrodes act as optical tweezers pushing the neighboring molecules closer together. These findings offer a nondestructive approach to regulate the interaction of the molecules, deepening the understanding of the mechanism of 𝜋–𝜋 interaction, and open an avenue to manipulate the relative position of extremely small objects down to the scale of single molecules.
dc.description.versionpublisheddeu
dc.identifier.doi10.1103/physrevlett.133.233001
dc.identifier.urihttps://kops.uni-konstanz.de/handle/123456789/71876
dc.language.isoeng
dc.subject.ddc530
dc.titleManipulating π-π Interactions between Single Molecules by Using Antenna Electrodes as Optical Tweezerseng
dc.typeJOURNAL_ARTICLE
dspace.entity.typePublication
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@article{Xu2024-12-02Manip-71876,
  title={Manipulating π-π Interactions between Single Molecules by Using Antenna Electrodes as Optical Tweezers},
  year={2024},
  doi={10.1103/physrevlett.133.233001},
  number={23},
  volume={133},
  issn={0031-9007},
  journal={Physical Review Letters},
  author={Xu, Xiaona and Qi, Qiang and Hu, Qihong and Ma, Liang and Emusani, Ramya and Zhang, Surong and Zhao, Xueyan and Tan, Min and Adijiang, Adila and Zhang, Wei and Ma, Ziwei and Tian, Guangjun and Scheer, Elke and Xiang, Dong},
  note={Article Number: 233001}
}
kops.citation.iso690XU, Xiaona, Qiang QI, Qihong HU, Liang MA, Ramya EMUSANI, Surong ZHANG, Xueyan ZHAO, Min TAN, Adila ADIJIANG, Wei ZHANG, Ziwei MA, Guangjun TIAN, Elke SCHEER, Dong XIANG, 2024. Manipulating π-π Interactions between Single Molecules by Using Antenna Electrodes as Optical Tweezers. In: Physical Review Letters. American Physical Society (APS). 2024, 133(23), 233001. ISSN 0031-9007. eISSN 1079-7114. Verfügbar unter: doi: 10.1103/physrevlett.133.233001deu
kops.citation.iso690XU, Xiaona, Qiang QI, Qihong HU, Liang MA, Ramya EMUSANI, Surong ZHANG, Xueyan ZHAO, Min TAN, Adila ADIJIANG, Wei ZHANG, Ziwei MA, Guangjun TIAN, Elke SCHEER, Dong XIANG, 2024. Manipulating π-π Interactions between Single Molecules by Using Antenna Electrodes as Optical Tweezers. In: Physical Review Letters. American Physical Society (APS). 2024, 133(23), 233001. ISSN 0031-9007. eISSN 1079-7114. Available under: doi: 10.1103/physrevlett.133.233001eng
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kops.sourcefieldPhysical Review Letters. American Physical Society (APS). 2024, <b>133</b>(23), 233001. ISSN 0031-9007. eISSN 1079-7114. Verfügbar unter: doi: 10.1103/physrevlett.133.233001deu
kops.sourcefield.plainPhysical Review Letters. American Physical Society (APS). 2024, 133(23), 233001. ISSN 0031-9007. eISSN 1079-7114. Verfügbar unter: doi: 10.1103/physrevlett.133.233001deu
kops.sourcefield.plainPhysical Review Letters. American Physical Society (APS). 2024, 133(23), 233001. ISSN 0031-9007. eISSN 1079-7114. Available under: doi: 10.1103/physrevlett.133.233001eng
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source.periodicalTitlePhysical Review Letters
source.publisherAmerican Physical Society (APS)

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