Publikation: Reversal of the stereoselectivity of [4 + 2]-cycloadditions by co-ordination of the heterodienophile to a transition metal fragment
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1989
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Journal of the Chemical Society, Chemical Communications. 1989(10), pp. 667-668. ISSN 0022-4936. Available under: doi: 10.1039/C39890000667
Zusammenfassung
Co-ordination of thio- and selenoaldehydes to a pentacarbonylmetal fragment results in a reversal of the endo selectivity in Diels–Alder reactions with conjugated cyclic dienes giving predominantly exo adducts.
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540 Chemie
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FISCHER, Helmut, Kornelia TREIER, Ulrike GERBING, Josef HOFMANN, 1989. Reversal of the stereoselectivity of [4 + 2]-cycloadditions by co-ordination of the heterodienophile to a transition metal fragment. In: Journal of the Chemical Society, Chemical Communications. 1989(10), pp. 667-668. ISSN 0022-4936. Available under: doi: 10.1039/C39890000667BibTex
@article{Fischer1989Rever-23549,
year={1989},
doi={10.1039/C39890000667},
title={Reversal of the stereoselectivity of [4 + 2]-cycloadditions by co-ordination of the heterodienophile to a transition metal fragment},
number={10},
issn={0022-4936},
journal={Journal of the Chemical Society, Chemical Communications},
pages={667--668},
author={Fischer, Helmut and Treier, Kornelia and Gerbing, Ulrike and Hofmann, Josef}
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<dcterms:abstract xml:lang="eng">Co-ordination of thio- and selenoaldehydes to a pentacarbonylmetal fragment results in a reversal of the endo selectivity in Diels–Alder reactions with conjugated cyclic dienes giving predominantly exo adducts.</dcterms:abstract>
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