Reversal of the stereoselectivity of [4 + 2]-cycloadditions by co-ordination of the heterodienophile to a transition metal fragment

Fischer, Helmut; Treier, Kornelia; Gerbing, Ulrike; Hofmann, Josef

Reversal of the stereoselectivity of [4 + 2]-cycloadditions by co-ordination of the heterodienophile to a transition metal fragment

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Date

1989

Authors

Fischer, Helmut

Treier, Kornelia

Gerbing, Ulrike

Hofmann, Josef

Publication type

Journal article

Published in

Journal of the Chemical Society, Chemical Communications ; 1989, 10. - pp. 667-668. - ISSN 0022-4936

Abstract

Co-ordination of thio- and selenoaldehydes to a pentacarbonylmetal fragment results in a reversal of the endo selectivity in Diels–Alder reactions with conjugated cyclic dienes giving predominantly exo adducts.

Subject (DDC)

540 Chemistry

Cite This

ISO 690

FISCHER, Helmut, Kornelia TREIER, Ulrike GERBING, Josef HOFMANN, 1989. Reversal of the stereoselectivity of [4 + 2]-cycloadditions by co-ordination of the heterodienophile to a transition metal fragment. In: Journal of the Chemical Society, Chemical Communications(10), pp. 667-668. ISSN 0022-4936. Available under: doi: 10.1039/C39890000667

BibTex

@article{Fischer1989Rever-23549,
  year={1989},
  doi={10.1039/C39890000667},
  title={Reversal of the stereoselectivity of [4 + 2]-cycloadditions by co-ordination of the heterodienophile to a transition metal fragment},
  number={10},
  issn={0022-4936},
  journal={Journal of the Chemical Society, Chemical Communications},
  pages={667--668},
  author={Fischer, Helmut and Treier, Kornelia and Gerbing, Ulrike and Hofmann, Josef}
}

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