@article{Liu2019-11-01DualP-47666,
  year={2019},
  doi={10.1021/acs.orglett.9b03321},
  title={Dual-Participation Protecting Group Solves the Anomeric Stereocontrol Problems in Glycosylation Reactions},
  number={21},
  volume={21},
  issn={1523-7060},
  journal={Organic Letters},
  pages={8713--8717},
  author={Liu, Hui and Hansen, Thomas and Zhou, Si-Yu and Wen, Guo-En and Liu, Xu-Xue and Zhang, Qing-Ju and Codée, Jeroen D. C. and Schmidt, Richard R. and Sun, Jian-Song}
}

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    <dc:contributor>Zhou, Si-Yu</dc:contributor>
    <dc:contributor>Hansen, Thomas</dc:contributor>
    <dcterms:issued>2019-11-01</dcterms:issued>
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    <dc:creator>Schmidt, Richard R.</dc:creator>
    <dc:contributor>Schmidt, Richard R.</dc:contributor>
    <dc:language>eng</dc:language>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2019-11-27T14:04:23Z</dc:date>
    <dc:contributor>Codée, Jeroen D. C.</dc:contributor>
    <dc:contributor>Zhang, Qing-Ju</dc:contributor>
    <dc:contributor>Liu, Xu-Xue</dc:contributor>
    <dc:creator>Zhang, Qing-Ju</dc:creator>
    <dc:creator>Liu, Hui</dc:creator>
    <dc:contributor>Sun, Jian-Song</dc:contributor>
    <dc:creator>Sun, Jian-Song</dc:creator>
    <dc:creator>Zhou, Si-Yu</dc:creator>
    <dcterms:title>Dual-Participation Protecting Group Solves the Anomeric Stereocontrol Problems in Glycosylation Reactions</dcterms:title>
    <dc:creator>Codée, Jeroen D. C.</dc:creator>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2019-11-27T14:04:23Z</dcterms:available>
    <dc:contributor>Wen, Guo-En</dc:contributor>
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    <dc:creator>Liu, Xu-Xue</dc:creator>
    <dc:creator>Hansen, Thomas</dc:creator>
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    <dcterms:abstract xml:lang="eng">The 2,2-dimethyl-2-(ortho-nitrophenyl)acetyl (DMNPA) group permits, via robust neighboring group participation (NGP) or long distance participation (LDP) effects, the stereocontrolled 1,2-trans, 1,2-cis, as well as β-2,6-dideoxy glycosidic bond generation, while suppressing the undesired orthoester byproduct formation. The robust stereocontrol capability of the DMNPA is due to the dual-participation effect from both the ester functionality and the nitro group, verified by control reactions and DFT calculations and further corroborated by X-ray spectroscopy.</dcterms:abstract>
    <dc:contributor>Liu, Hui</dc:contributor>
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