Geodesic-Planar Conjugates : Substituted Buckybowls - Synthesis, Photoluminescence and Electrochemistry

Lade...
Vorschaubild
Dateien
Bayer_2-diz3kpuyltkl8.pdf
Bayer_2-diz3kpuyltkl8.pdfGröße: 2.31 MBDownloads: 213
Datum
2020
Herausgeber:innen
Kontakt
ISSN der Zeitschrift
Electronic ISSN
ISBN
Bibliografische Daten
Verlag
Schriftenreihe
Auflagebezeichnung
ArXiv-ID
Internationale Patentnummer
Link zur Lizenz
Angaben zur Forschungsförderung
Projekt
Open Access-Veröffentlichung
Open Access Hybrid
Sammlungen
Core Facility der Universität Konstanz
Gesperrt bis
Titel in einer weiteren Sprache
Forschungsvorhaben
Organisationseinheiten
Zeitschriftenheft
Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published
Erschienen in
Chemistry - A European Journal. Wiley. 2020, 26(72), pp. 17546-17558. ISSN 0947-6539. eISSN 1521-3765. Available under: doi: 10.1002/chem.202003605
Zusammenfassung

Cross coupling products of bowl-shaped as -indaceno[3,2,1,8,7,6- pqrstuv ]picene (Idpc) and different planar arenes and ethynyl-arenes were synthesized by either Suzuki or Sonogashira cross coupling. Photoluminescence as well as electrochemical properties of all products were investigated and complemented by time-dependent quantum chemical calculations. UV/vis- spectroelectrochemistry investigations of the directly linked (Idpc) 2 ( 9 ) uncovered the formation of 65 % (Idpc) 2 •- as the major reduction product. All coupling products showed fluorescence. Ferrocene-1-yl-Idpc was structurally characterized by X-ray diffraction and is a rare example of a ferrocene-containing buckybowl exhibiting luminescence.

Zusammenfassung in einer weiteren Sprache
Fachgebiet (DDC)
540 Chemie
Schlagwörter
Konferenz
Rezension
undefined / . - undefined, undefined
Zitieren
ISO 690BAYER, Johannes, Jan HERBERGER, Lukas HOLZ, Rainer F. WINTER, Thomas HUHN, 2020. Geodesic-Planar Conjugates : Substituted Buckybowls - Synthesis, Photoluminescence and Electrochemistry. In: Chemistry - A European Journal. Wiley. 2020, 26(72), pp. 17546-17558. ISSN 0947-6539. eISSN 1521-3765. Available under: doi: 10.1002/chem.202003605
BibTex
@article{Bayer2020-12-23Geode-50710,
  year={2020},
  doi={10.1002/chem.202003605},
  title={Geodesic-Planar Conjugates : Substituted Buckybowls - Synthesis, Photoluminescence and Electrochemistry},
  number={72},
  volume={26},
  issn={0947-6539},
  journal={Chemistry - A European Journal},
  pages={17546--17558},
  author={Bayer, Johannes and Herberger, Jan and Holz, Lukas and Winter, Rainer F. and Huhn, Thomas}
}
RDF
<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/50710">
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/50710/1/Bayer_2-diz3kpuyltkl8.pdf"/>
    <dc:creator>Bayer, Johannes</dc:creator>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2020-09-07T14:55:10Z</dcterms:available>
    <dc:creator>Huhn, Thomas</dc:creator>
    <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/50710"/>
    <dc:contributor>Herberger, Jan</dc:contributor>
    <dcterms:rights rdf:resource="http://creativecommons.org/licenses/by-nc-nd/4.0/"/>
    <dc:language>eng</dc:language>
    <dc:contributor>Bayer, Johannes</dc:contributor>
    <dc:contributor>Huhn, Thomas</dc:contributor>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dc:contributor>Winter, Rainer F.</dc:contributor>
    <dc:rights>Attribution-NonCommercial-NoDerivatives 4.0 International</dc:rights>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/50710/1/Bayer_2-diz3kpuyltkl8.pdf"/>
    <dcterms:title>Geodesic-Planar Conjugates : Substituted Buckybowls - Synthesis, Photoluminescence and Electrochemistry</dcterms:title>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dcterms:abstract xml:lang="eng">Cross coupling products of bowl-shaped as -indaceno[3,2,1,8,7,6- pqrstuv ]picene (Idpc) and different planar arenes and ethynyl-arenes were synthesized by either Suzuki or Sonogashira cross coupling. Photoluminescence as well as electrochemical properties of all products were investigated and complemented by time-dependent quantum chemical calculations. UV/vis- spectroelectrochemistry investigations of the directly linked (Idpc) 2 ( 9 ) uncovered the formation of 65 % (Idpc) 2 •- as the major reduction product. All coupling products showed fluorescence. Ferrocene-1-yl-Idpc was structurally characterized by X-ray diffraction and is a rare example of a ferrocene-containing buckybowl exhibiting luminescence.</dcterms:abstract>
    <dcterms:issued>2020-12-23</dcterms:issued>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2020-09-07T14:55:10Z</dc:date>
    <dc:creator>Winter, Rainer F.</dc:creator>
    <dc:creator>Holz, Lukas</dc:creator>
    <dc:contributor>Holz, Lukas</dc:contributor>
    <dc:creator>Herberger, Jan</dc:creator>
  </rdf:Description>
</rdf:RDF>
Interner Vermerk
xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter
Kontakt
URL der Originalveröffentl.
Prüfdatum der URL
Prüfungsdatum der Dissertation
Finanzierungsart
Kommentar zur Publikation
Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Ja
Begutachtet
Ja
Diese Publikation teilen