Photoionization thresholds of rare gas clusters

Ganteför, Gerd; Bröker, Günther; Holub-Krappe, Elizabeta; Ding, Adalbert

Photoionization thresholds of rare gas clusters

Files

JChemPhys911989.pdf(860.3 KB)

Date

1989

Authors

Ganteför, Gerd

Bröker, Günther

Holub-Krappe, Elizabeta

Ding, Adalbert

Publication type

Journal article

Published in

Journal of Chemical Physics ; 91 (1989), 12. - pp. 7972-7977

Abstract

Photoionization efficiency curves of rare gas clusters generated by supersonic expansion of pure argon, krypton, and xenon gas have been measured as a function of photon energy using light from the Berlin Electron Synchrotron Facility (BESSY). Assuming that the relative shapes of the efficiency curves are independent of cluster size, ionization potentials for each cluster can be extracted from the data by using the known absolute ionization thresholds of the dimer or trimer ions. The data agree with the model that ionic clusters are composed of an ionic substructure surrounded by shells of atoms. In particular, it has been confirmed that Ar3+ is the central substructure in Arn+ for n

Subject (DDC)

530 Physics

Keywords

Argon complexes,Krypton complexes,Xenon complexes,Atomic clusters,Photoionization,Bessy storage ring,Synchrotron radiation,Mass spectra

Cite This

ISO 690

GANTEFÖR, Gerd, Günther BRÖKER, Elizabeta HOLUB-KRAPPE, Adalbert DING, 1989. Photoionization thresholds of rare gas clusters. In: Journal of Chemical Physics. 91(12), pp. 7972-7977. Available under: doi: 10.1063/1.457215

BibTex

@article{Gantefor1989Photo-4701,
  year={1989},
  doi={10.1063/1.457215},
  title={Photoionization thresholds of rare gas clusters},
  number={12},
  volume={91},
  journal={Journal of Chemical Physics},
  pages={7972--7977},
  author={Ganteför, Gerd and Bröker, Günther and Holub-Krappe, Elizabeta and Ding, Adalbert}
}

RDF

<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/4701">
    <dcterms:title>Photoionization thresholds of rare gas clusters</dcterms:title>
    <dc:language>eng</dc:language>
    <dc:creator>Ding, Adalbert</dc:creator>
    <dc:creator>Bröker, Günther</dc:creator>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/4701/1/JChemPhys911989.pdf"/>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dc:rights>terms-of-use</dc:rights>
    <dc:creator>Ganteför, Gerd</dc:creator>
    <dc:creator>Holub-Krappe, Elizabeta</dc:creator>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
    <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
    <dc:contributor>Holub-Krappe, Elizabeta</dc:contributor>
    <dc:contributor>Ganteför, Gerd</dc:contributor>
    <dc:contributor>Bröker, Günther</dc:contributor>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
    <dc:contributor>Ding, Adalbert</dc:contributor>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T14:49:42Z</dc:date>
    <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/4701"/>
    <dcterms:bibliographicCitation>First publ. in: Journal of Chemical Physics 91 (1989), 12, pp. 7972-7977</dcterms:bibliographicCitation>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T14:49:42Z</dcterms:available>
    <dcterms:abstract xml:lang="eng">Photoionization efficiency curves of rare gas clusters generated by supersonic expansion of pure argon, krypton, and xenon gas have been measured as a function of photon energy using light from the Berlin Electron Synchrotron Facility (BESSY). Assuming that the relative shapes of the efficiency curves are independent of cluster size, ionization potentials for each cluster can be extracted from the data by using the known absolute ionization thresholds of the dimer or trimer ions. The data agree with the model that ionic clusters are composed of an ionic substructure surrounded by shells of atoms. In particular, it has been confirmed that Ar3+ is the central substructure in Arn+ for n</dcterms:abstract>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/4701/1/JChemPhys911989.pdf"/>
    <dcterms:issued>1989</dcterms:issued>
    <dc:format>application/pdf</dc:format>
  </rdf:Description>
</rdf:RDF>

Bibliography of Konstanz

No