Photoionization thresholds of rare gas clusters
Photoionization thresholds of rare gas clusters
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1989
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Journal of Chemical Physics ; 91 (1989), 12. - pp. 7972-7977
Abstract
Photoionization efficiency curves of rare gas clusters generated by supersonic expansion of pure argon, krypton, and xenon gas have been measured as a function of photon energy using light from the Berlin Electron Synchrotron Facility (BESSY). Assuming that the relative shapes of the efficiency curves are independent of cluster size, ionization potentials for each cluster can be extracted from the data by using the known absolute ionization thresholds of the dimer or trimer ions. The data agree with the model that ionic clusters are composed of an ionic substructure surrounded by shells of atoms. In particular, it has been confirmed that Ar3+ is the central substructure in Arn+ for n
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530 Physics
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Argon complexes,Krypton complexes,Xenon complexes,Atomic clusters,Photoionization,Bessy storage ring,Synchrotron radiation,Mass spectra
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GANTEFÖR, Gerd, Günther BRÖKER, Elizabeta HOLUB-KRAPPE, Adalbert DING, 1989. Photoionization thresholds of rare gas clusters. In: Journal of Chemical Physics. 91(12), pp. 7972-7977. Available under: doi: 10.1063/1.457215BibTex
@article{Gantefor1989Photo-4701, year={1989}, doi={10.1063/1.457215}, title={Photoionization thresholds of rare gas clusters}, number={12}, volume={91}, journal={Journal of Chemical Physics}, pages={7972--7977}, author={Ganteför, Gerd and Bröker, Günther and Holub-Krappe, Elizabeta and Ding, Adalbert} }
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