@article{Winter1997AzaCo-13860,
  year={1997},
  doi={10.1021/om9704511},
  title={The Aza-Cope Rearrangement in Transition Metal Complexes. Construction of an Unsaturated C7-Ligand from Butadiyne and an Allylic Amine},
  number={20},
  volume={16},
  issn={0276-7333},
  journal={Organometallics},
  pages={4248--4250},
  author={Winter, Rainer F. and Hornung, Fridmann}
}

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    <dcterms:abstract xml:lang="eng">cis-RuCl2(L2)2 reacts with butadiyne in the presence of NaPF6 to give the butatrienylidene intermediate trans-[RuCl(L2)2CCCCH2]+, which can be trapped with tertiary amines to afford the ammoniobutenynyl complexes trans-[RuCl(L2)2CCC(NR3) CH2]+ (L2 = dppm; R = Et, Pr). The respective N-allyl derivatives trans-[RuCl(L2)2CCC((NMe2)allyl) CH2]+ (L = dppm, depe) rearrange under ambient conditions via an aza-Cope process to the amino-substituted allenylidene complexes trans-[RuCl(L2)2 CCC(NMe2)(CH2)2CHCH2]+.</dcterms:abstract>
    <dc:contributor>Hornung, Fridmann</dc:contributor>
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    <dcterms:title>The Aza-Cope Rearrangement in Transition Metal Complexes. Construction of an Unsaturated C7-Ligand from Butadiyne and an Allylic Amine</dcterms:title>
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    <dcterms:bibliographicCitation>First publ. in: Organometallics 16 (1997), 20, pp. 4248-4250</dcterms:bibliographicCitation>
    <dc:creator>Winter, Rainer F.</dc:creator>
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