N2 chemisorption to W-n nanoclusters : molecular versus dissociative chemisorption

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2003
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Kim, Young Dok
Stolcic, Davor
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Chemical Physics Letters ; 380 (2003), 3-4. - pp. 359-365
Abstract
Comparative studies on adsorption of atomic and molecular nitrogen indicate that in contrast to the previous results from tungsten bulk crystals, molecular chemisorption of N2 is more stable than dissociative ones on tungsten anion clusters consisting of 8 atoms or less. Our result provides a new aspect in chemisorption on metal clusters, namely the energetically preferred channel of chemisorption dissociative versus molecular might be different for metal clusters and bulk surfaces.
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ISO 690KIM, Young Dok, Davor STOLCIC, Matthias FISCHER, Gerd GANTEFÖR, 2003. N2 chemisorption to W-n nanoclusters : molecular versus dissociative chemisorption. In: Chemical Physics Letters. 380(3-4), pp. 359-365. Available under: doi: 10.1016/j.cplett.2003.09.034
BibTex
@article{Kim2003chemi-8962,
  year={2003},
  doi={10.1016/j.cplett.2003.09.034},
  title={N2 chemisorption to W-n nanoclusters : molecular versus dissociative chemisorption},
  number={3-4},
  volume={380},
  journal={Chemical Physics Letters},
  pages={359--365},
  author={Kim, Young Dok and Stolcic, Davor and Fischer, Matthias and Ganteför, Gerd}
}
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