Electronic shells or molecular orbitals : photoelectron spectra of Agn- clusters
Electronic shells or molecular orbitals : photoelectron spectra of Agn- clusters
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1995
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Journal of Chemical Physics ; 102 (1995), 16. - pp. 6406-6422
Abstract
Photoelectron spectra of Ag - n clusters with n=1–21 recorded at different photon energies (hnu=4.025, 4.66, 5.0, and 6.424 eV) are presented. Various features in the spectra of Ag - 2–Ag - 9 can be assigned to electronic transitions predicted from quantum chemical ab initio calculations. While this comparison with the quantum chemical calculations yields a detailed and quantitative understanding of the electronic structure of each individual cluster, a discussion in terms of the shell model is able to explain trends and dominant patterns in the entire series of spectra up to Ag - 21.
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530 Physics
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Photoelectron spectroscopy,silver ions,ion pairs,energy range,electronic strucure,shell models,ab initio calculations
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HANDSCHUH, Haiko, Chia-Yen CHA, Paul S. BECHTHOLD, Gerd GANTEFÖR, Wolfgang EBERHARDT, 1995. Electronic shells or molecular orbitals : photoelectron spectra of Agn- clusters. In: Journal of Chemical Physics. 102(16), pp. 6406-6422. Available under: doi: 10.1063/1.469356BibTex
@article{Handschuh1995Elect-9497, year={1995}, doi={10.1063/1.469356}, title={Electronic shells or molecular orbitals : photoelectron spectra of Agn- clusters}, number={16}, volume={102}, journal={Journal of Chemical Physics}, pages={6406--6422}, author={Handschuh, Haiko and Cha, Chia-Yen and Bechthold, Paul S. and Ganteför, Gerd and Eberhardt, Wolfgang} }
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