Hydrothermal Generation of Conjugated Polymers Using the Example of Pyrrone Polymers and Polybenzimidazoles

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2020
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Taublaender, M. Josef
Mezzavilla, Stefano
Thiele, Sophia
Glöcklhofer, Florian
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Various polyimides and polyamides have recently been prepared via hydrothermal synthesis in nothing but H2 O under high-pressure and high-temperature conditions. However, none of the prepared polymers feature a truly conjugated polymer backbone. Here, we report on an expansion of the synthetic scope of this straightforward and inherently environmentally friendly polymerization technique to the generation of conjugated polymers. Selected representatives of two different polymer classes, pyrrone polymers and polybenzimidazoles, were generated hydrothermally. We present a mechanistic discussion of the polymer formation process as well as an electrochemical characterization of the most promising product.

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ISO 690TAUBLAENDER, M. Josef, Stefano MEZZAVILLA, Sophia THIELE, Florian GLÖCKLHOFER, Miriam M. UNTERLASS, 2020. Hydrothermal Generation of Conjugated Polymers Using the Example of Pyrrone Polymers and Polybenzimidazoles. In: Angewandte Chemie International Edition. Wiley-Blackwell. 2020, 59(35), pp. 15050-15060. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/anie.202000367
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@article{Taublaender2020-08-24Hydro-54813,
  year={2020},
  doi={10.1002/anie.202000367},
  title={Hydrothermal Generation of Conjugated Polymers Using the Example of Pyrrone Polymers and Polybenzimidazoles},
  number={35},
  volume={59},
  issn={1433-7851},
  journal={Angewandte Chemie International Edition},
  pages={15050--15060},
  author={Taublaender, M. Josef and Mezzavilla, Stefano and Thiele, Sophia and Glöcklhofer, Florian and Unterlass, Miriam M.}
}
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