Noncovalent Interactions in o-Fluorinated Post-titanocene Living Ethylene Polymerization Catalyst

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2010
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Bryliakov, Konstantin P.
Talsi, Evgenii P.
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Organometallics. 2010, 29(20), pp. 4428-4430. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om100729y
Zusammenfassung

Summary: Multinuclear NMR spectroscopic studies of polymerization-active species generated by activation of o-F-substituted and nonsubstituted bis(enolatoimine) titanium complexes with MAO evidence a noncovalent interaction of the o-F moieties with the metal center, which is likely to facilitate living ethylene polymerization via suppression of chain transfer and of β-hydrogen transfer processes.

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ISO 690BRYLIAKOV, Konstantin P., Evgenii P. TALSI, Heiko M. MÖLLER, Moritz C. BAIER, Stefan MECKING, 2010. Noncovalent Interactions in o-Fluorinated Post-titanocene Living Ethylene Polymerization Catalyst. In: Organometallics. 2010, 29(20), pp. 4428-4430. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om100729y
BibTex
@article{Bryliakov2010Nonco-9572,
  year={2010},
  doi={10.1021/om100729y},
  title={Noncovalent Interactions in o-Fluorinated Post-titanocene Living Ethylene Polymerization Catalyst},
  number={20},
  volume={29},
  issn={0276-7333},
  journal={Organometallics},
  pages={4428--4430},
  author={Bryliakov, Konstantin P. and Talsi, Evgenii P. and Möller, Heiko M. and Baier, Moritz C. and Mecking, Stefan}
}
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