ansa-metallocene derivatives : VII. Synthesis and crystal structure of a chiral ansa-zirconocene derivative with ethylene-bridged tetrahydroindenyl ligands
ansa-metallocene derivatives : VII. Synthesis and crystal structure of a chiral ansa-zirconocene derivative with ethylene-bridged tetrahydroindenyl ligands
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1985
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Journal of Organometallic Chemistry ; 288 (1985), 1. - pp. 63-67. - ISSN 0022-328X
Abstract
The chiral ansa-zirconocene derivative ethylenebis(4,5,6,7-tetrahydro-1-indenyl)-zirconium(IV) dichloride has been prepared by reaction of dilithiobis(indenyl)ethane with ZrCl4 and subsequent hydrogenation. The product has been shown to be the 1-R,S rather than meso-metal-ring linkage stereoisomer by an X-ray determination of the molecular structure.
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WILD, Ferdinand R. W. P., Marek WASIUCIONEK, Gottfried HUTTNER, Hans-Herbert BRINTZINGER, 1985. ansa-metallocene derivatives : VII. Synthesis and crystal structure of a chiral ansa-zirconocene derivative with ethylene-bridged tetrahydroindenyl ligands. In: Journal of Organometallic Chemistry. 288(1), pp. 63-67. ISSN 0022-328X. Available under: doi: 10.1016/0022-328X(85)80104-2BibTex
@article{Wild1985ansam-23993, year={1985}, doi={10.1016/0022-328X(85)80104-2}, title={ansa-metallocene derivatives : VII. Synthesis and crystal structure of a chiral ansa-zirconocene derivative with ethylene-bridged tetrahydroindenyl ligands}, number={1}, volume={288}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={63--67}, author={Wild, Ferdinand R. W. P. and Wasiucionek, Marek and Huttner, Gottfried and Brintzinger, Hans-Herbert} }
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