ansa-metallocene derivatives : VII. Synthesis and crystal structure of a chiral ansa-zirconocene derivative with ethylene-bridged tetrahydroindenyl ligands

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1985
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Wild, Ferdinand R. W. P.
Wasiucionek, Marek
Huttner, Gottfried
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The chiral ansa-zirconocene derivative ethylenebis(4,5,6,7-tetrahydro-1-indenyl)-zirconium(IV) dichloride has been prepared by reaction of dilithiobis(indenyl)ethane with ZrCl4 and subsequent hydrogenation. The product has been shown to be the 1-R,S rather than meso-metal-ring linkage stereoisomer by an X-ray determination of the molecular structure.

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ISO 690WILD, Ferdinand R. W. P., Marek WASIUCIONEK, Gottfried HUTTNER, Hans-Herbert BRINTZINGER, 1985. ansa-metallocene derivatives : VII. Synthesis and crystal structure of a chiral ansa-zirconocene derivative with ethylene-bridged tetrahydroindenyl ligands. In: Journal of Organometallic Chemistry. 1985, 288(1), pp. 63-67. ISSN 0022-328X. Available under: doi: 10.1016/0022-328X(85)80104-2
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@article{Wild1985ansam-23993,
  year={1985},
  doi={10.1016/0022-328X(85)80104-2},
  title={ansa-metallocene derivatives : VII. Synthesis and crystal structure of a chiral ansa-zirconocene derivative with ethylene-bridged tetrahydroindenyl ligands},
  number={1},
  volume={288},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={63--67},
  author={Wild, Ferdinand R. W. P. and Wasiucionek, Marek and Huttner, Gottfried and Brintzinger, Hans-Herbert}
}
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