ansa-metallocene derivatives : VII. Synthesis and crystal structure of a chiral ansa-zirconocene derivative with ethylene-bridged tetrahydroindenyl ligands

Wild, Ferdinand R. W. P.; Wasiucionek, Marek; Huttner, Gottfried; Brintzinger, Hans-Herbert

ansa-metallocene derivatives : VII. Synthesis and crystal structure of a chiral ansa-zirconocene derivative with ethylene-bridged tetrahydroindenyl ligands

Files

Wild_239939.pdf(215.98 KB)

Date

1985

Authors

Wild, Ferdinand R. W. P.

Wasiucionek, Marek

Huttner, Gottfried

Brintzinger, Hans-Herbert

Publication type

Journal article

Published in

Journal of Organometallic Chemistry ; 288 (1985), 1. - pp. 63-67. - ISSN 0022-328X

Abstract

The chiral ansa-zirconocene derivative ethylenebis(4,5,6,7-tetrahydro-1-indenyl)-zirconium(IV) dichloride has been prepared by reaction of dilithiobis(indenyl)ethane with ZrCl₄ and subsequent hydrogenation. The product has been shown to be the 1-R,S rather than meso-metal-ring linkage stereoisomer by an X-ray determination of the molecular structure.

Subject (DDC)

540 Chemistry

Cite This

ISO 690

WILD, Ferdinand R. W. P., Marek WASIUCIONEK, Gottfried HUTTNER, Hans-Herbert BRINTZINGER, 1985. ansa-metallocene derivatives : VII. Synthesis and crystal structure of a chiral ansa-zirconocene derivative with ethylene-bridged tetrahydroindenyl ligands. In: Journal of Organometallic Chemistry. 288(1), pp. 63-67. ISSN 0022-328X. Available under: doi: 10.1016/0022-328X(85)80104-2

BibTex

@article{Wild1985ansam-23993,
  year={1985},
  doi={10.1016/0022-328X(85)80104-2},
  title={ansa-metallocene derivatives : VII. Synthesis and crystal structure of a chiral ansa-zirconocene derivative with ethylene-bridged tetrahydroindenyl ligands},
  number={1},
  volume={288},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={63--67},
  author={Wild, Ferdinand R. W. P. and Wasiucionek, Marek and Huttner, Gottfried and Brintzinger, Hans-Herbert}
}

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