Publikation:

Living Aqueous Microemulsion Polymerization of Ethylene with Robust Ni(II) Phosphinophenolato Catalysts

Vorschaubild

Dateien

Lin_2-jh5capdzbn735.pdf
Lin_2-jh5capdzbn735.pdfGröße: 280.85 KBDownloads: 208

Datum

2021

Autor:innen

Herausgeber:innen

Kontakt

ISSN der Zeitschrift

Electronic ISSN

ISBN

Bibliografische Daten

Verlag

Schriftenreihe

Auflagebezeichnung

URI (zitierfähiger Link)
http://nbn-resolving.de/urn:nbn:de:bsz:352-2-jh5capdzbn735
DOI (zitierfähiger Link)
https://doi.org/10.1021/jacs.1c10488
ArXiv-ID

Internationale Patentnummer

Link zur Lizenz
Urheberrechtlich geschützt

Angaben zur Forschungsförderung

Projekt

Open Access-Veröffentlichung
Open Access Green

Sammlungen

Chemie: Publikationen
Core Facility der Universität Konstanz

Gesperrt bis

Titel in einer weiteren Sprache

Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published

Erschienen in

Journal of the American Chemical Society. American Chemical Society (ACS). 2021, 143(49), pp. 20605-20608. ISSN 0002-7863. eISSN 1520-5126. Available under: doi: 10.1021/jacs.1c10488

Zusammenfassung

Due to chain transfer events being competitive with chain growth, ethylene polymerization by P,O-chelated Ni(II) complexes usually affords low molecular weight polymers or oligomers. We now show that appropriately bulky substituted phosphinophenolato Ni(II) can polymerize in a living fashion, virtually devoid of chain transfer. Aqueous polymerizations with microemulsions of [κ2-P,O-2-(2-(2',6'-(MeO)2C6H3)C6H4)(Ph)P-6-(3',5'-(CF3)2C6H3)C6H3O-NiMe(pyridine)] (3) at 30 °C yield polyethylenes with narrow molecular weight distributions (Mw/Mn 1.02 to 1.34) and ultrahigh molecular weights (up to 2 × 106) in the form of aqueous nanoparticle dispersions. Catalyst stability and activity are maintained up to 70 °C in water.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
540 Chemie

Schlagwörter

Konferenz

Rezension
undefined / . - undefined, undefined

Forschungsvorhaben

Organisationseinheiten

Zeitschriftenheft

Verknüpfte Datensätze

Zitieren

ISO 690LIN, Fei, Tobias O. MORGEN, Stefan MECKING, 2021. Living Aqueous Microemulsion Polymerization of Ethylene with Robust Ni(II) Phosphinophenolato Catalysts. In: Journal of the American Chemical Society. American Chemical Society (ACS). 2021, 143(49), pp. 20605-20608. ISSN 0002-7863. eISSN 1520-5126. Available under: doi: 10.1021/jacs.1c10488
BibTex
@article{Lin2021-12-15Livin-55985,
  year={2021},
  doi={10.1021/jacs.1c10488},
  title={Living Aqueous Microemulsion Polymerization of Ethylene with Robust Ni(II) Phosphinophenolato Catalysts},
  number={49},
  volume={143},
  issn={0002-7863},
  journal={Journal of the American Chemical Society},
  pages={20605--20608},
  author={Lin, Fei and Morgen, Tobias O. and Mecking, Stefan}
}
RDF
<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/55985">
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dc:rights>terms-of-use</dc:rights>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2021-12-22T10:26:55Z</dc:date>
    <dc:contributor>Morgen, Tobias O.</dc:contributor>
    <dc:language>eng</dc:language>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/55985/1/Lin_2-jh5capdzbn735.pdf"/>
    <dc:creator>Mecking, Stefan</dc:creator>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2021-12-22T10:26:55Z</dcterms:available>
    <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dcterms:title>Living Aqueous Microemulsion Polymerization of Ethylene with Robust Ni(II) Phosphinophenolato Catalysts</dcterms:title>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/55985/1/Lin_2-jh5capdzbn735.pdf"/>
    <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/55985"/>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dcterms:issued>2021-12-15</dcterms:issued>
    <dc:creator>Lin, Fei</dc:creator>
    <dc:creator>Morgen, Tobias O.</dc:creator>
    <dc:contributor>Lin, Fei</dc:contributor>
    <dcterms:abstract xml:lang="eng">Due to chain transfer events being competitive with chain growth, ethylene polymerization by P,O-chelated Ni(II) complexes usually affords low molecular weight polymers or oligomers. We now show that appropriately bulky substituted phosphinophenolato Ni(II) can polymerize in a living fashion, virtually devoid of chain transfer. Aqueous polymerizations with microemulsions of [κ&lt;sup&gt;2&lt;/sup&gt;-P,O-2-(2-(2',6'-(MeO)&lt;sub&gt;2&lt;/sub&gt;C&lt;sub&gt;6&lt;/sub&gt;H&lt;sub&gt;3&lt;/sub&gt;)C6H4)(Ph)P-6-(3',5'-(CF&lt;sub&gt;3&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;C&lt;sub&gt;6&lt;/sub&gt;H&lt;sub&gt;3&lt;/sub&gt;)C&lt;sub&gt;6&lt;/sub&gt;H&lt;sub&gt;3&lt;/sub&gt;O-NiMe(pyridine)] (3) at 30 °C yield polyethylenes with narrow molecular weight distributions (M&lt;sub&gt;w&lt;/sub&gt;/M&lt;sub&gt;n&lt;/sub&gt; 1.02 to 1.34) and ultrahigh molecular weights (up to 2 × 10&lt;sup&gt;6&lt;/sup&gt;) in the form of aqueous nanoparticle dispersions. Catalyst stability and activity are maintained up to 70 °C in water.</dcterms:abstract>
    <dc:contributor>Mecking, Stefan</dc:contributor>
  </rdf:Description>
</rdf:RDF>

Interner Vermerk

xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter

Kontakt
URL der Originalveröffentl.

Prüfdatum der URL

Prüfungsdatum der Dissertation

Finanzierungsart

Kommentar zur Publikation

Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Ja
Begutachtet
Ja
Diese Publikation teilen