@article{Liu2015Elect-30995,
  year={2015},
  doi={10.1021/acsami.5b01792},
  title={Electric Transport Properties of Surface-Anchored Metal-Organic Frameworks and the Effect of Ferrocene Loading},
  number={18},
  volume={7},
  issn={1944-8244},
  journal={ACS Applied Materials & Interfaces},
  pages={9824--9830},
  author={Liu, Jianxi and Wächter, Tobias and Irmler, Andreas and Weidler, Peter G. and Gliemann, Hartmut and Pauly, Fabian and Mugnaini, Veronica and Zharnikov, Michael and Wöll, Christof}
}

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    <dc:creator>Weidler, Peter G.</dc:creator>
    <dc:creator>Gliemann, Hartmut</dc:creator>
    <dc:contributor>Zharnikov, Michael</dc:contributor>
    <dc:contributor>Pauly, Fabian</dc:contributor>
    <dc:contributor>Irmler, Andreas</dc:contributor>
    <dc:contributor>Wöll, Christof</dc:contributor>
    <dcterms:issued>2015</dcterms:issued>
    <dcterms:title>Electric Transport Properties of Surface-Anchored Metal-Organic Frameworks and the Effect of Ferrocene Loading</dcterms:title>
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    <dc:contributor>Gliemann, Hartmut</dc:contributor>
    <dc:contributor>Wächter, Tobias</dc:contributor>
    <dc:language>eng</dc:language>
    <dc:creator>Mugnaini, Veronica</dc:creator>
    <dc:creator>Zharnikov, Michael</dc:creator>
    <dc:contributor>Liu, Jianxi</dc:contributor>
    <dc:contributor>Mugnaini, Veronica</dc:contributor>
    <dc:creator>Irmler, Andreas</dc:creator>
    <dc:creator>Pauly, Fabian</dc:creator>
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    <dcterms:abstract xml:lang="eng">Understanding of the electric transport through surface-anchored metal–organic frameworks (SURMOFs) is important both from a fundamental perspective as well as with regards to possible future applications in electronic devices. To address this mostly unexplored subject, we integrated a series of representative SURMOF thin films, formed by copper nodes and trimesic acid and known as HKUST-1, in a mercury-drop-based tunneling junction. Although the transport properties of these SURMOFs are analogous to those of hybrid metal–organic molecular wires, manifested by a very low value of the tunneling decay constant (β ≈ 0.006 Å&lt;sup&gt;–1&lt;/sup&gt;), they are at the same time found to be consistent with a linear increase of resistance with film thickness. Upon loading of SURMOF pores with ferrocene (Fc), a noticeable increase in transport current was observed. A transport model and ab initio electronic structure calculations were used to reveal a hopping transport mechanism and to relate the changes upon Fc loading to those of the electronic and vibrational structures of the SURMOF films.</dcterms:abstract>
    <dc:creator>Liu, Jianxi</dc:creator>
    <dc:creator>Wächter, Tobias</dc:creator>
    <dc:creator>Wöll, Christof</dc:creator>
    <dc:contributor>Weidler, Peter G.</dc:contributor>
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