N-(17-Acyloxy-acyl)-glutamines : novel surfactants from oral secretions of lepidopteran larvae
N-(17-Acyloxy-acyl)-glutamines : novel surfactants from oral secretions of lepidopteran larvae
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2003
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Boland, Wilhelm
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The Journal of Organic Chemistry ; 68 (2003), 23. - pp. 8743-8749. - ISSN 0022-3263
Abstract
N-(17-Acyloxy-acyl)-glutamine conjugates such as N-(17-linolenoyloxy-linolenoyl)-glutamine (6), N-(17-linolenoyloxy-linoleoyl)-glutamine (7), N-(17-linoleoyloxy-linolenoyl)-glutamine (8), and N-(17-linoleoyloxy-linoleoyl)-glutamine (9) were identified as novel surfactants in the oral secretion of several lepidopteran larvae (S. exigua, S. littoralis, S. frugiperda, and H. virescens) by LC-MS/MS and chemical degradation. Authentic reference compounds were synthesized via a dissymmetric bis-Wittig approach and confirmed the assigned structures.
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570 Biosciences, Biology
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SPITELLER, Dieter, Wilhelm BOLAND, 2003. N-(17-Acyloxy-acyl)-glutamines : novel surfactants from oral secretions of lepidopteran larvae. In: The Journal of Organic Chemistry. 68(23), pp. 8743-8749. ISSN 0022-3263. Available under: doi: 10.1021/jo0342525BibTex
@article{Spiteller2003-11-14N17Ac-15550, year={2003}, doi={10.1021/jo0342525}, title={N-(17-Acyloxy-acyl)-glutamines : novel surfactants from oral secretions of lepidopteran larvae}, number={23}, volume={68}, issn={0022-3263}, journal={The Journal of Organic Chemistry}, pages={8743--8749}, author={Spiteller, Dieter and Boland, Wilhelm} }
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