Synthesis of nickel hexacyanoferrate nanocubes with tuneable dimensions via temperature-controlled Ni2+-citrate complexation

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2020
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urn:nbn:de:bsz:352-2-nugmu7th94aj1
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10.1039/D0CC04628K
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Chemical Communications ; 56 (2020), 92. - pp. 14439-14442. - Royal Society of Chemistry (RSC). - ISSN 0009-241X. - eISSN 1364-548X
Abstract
The citrate-assisted growth of nickel hexacyanoferrate (NiHCF) nanocubes was investigated. Control over the complexation of Ni2+ ions with citrate at different temperatures enabled fine tuning of the nanocrystal (NC) dimensions and their self-assembly into mesocrystals. Our results introduce new concepts towards the synthesis of NiHCF NCs, potentially applicable to other members of the Prussian blue analogues family.
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ISO 690KESSLER, Sascha, Guillermo GONZALEZ-RUBIO, Elrike R. REINALTER, Michael KOVERMANN, Helmut CÖLFEN, 2020. Synthesis of nickel hexacyanoferrate nanocubes with tuneable dimensions via temperature-controlled Ni2+-citrate complexation. In: Chemical Communications. Royal Society of Chemistry (RSC). 56(92), pp. 14439-14442. ISSN 0009-241X. eISSN 1364-548X. Available under: doi: 10.1039/D0CC04628K
BibTex
@article{Keler2020-11-19Synth-51768,
  year={2020},
  doi={10.1039/D0CC04628K},
  title={Synthesis of nickel hexacyanoferrate nanocubes with tuneable dimensions via temperature-controlled Ni<sup>2+</sup>-citrate complexation},
  number={92},
  volume={56},
  issn={0009-241X},
  journal={Chemical Communications},
  pages={14439--14442},
  author={Keßler, Sascha and Gonzalez-Rubio, Guillermo and Reinalter, Elrike R. and Kovermann, Michael and Cölfen, Helmut}
}
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    <dcterms:abstract xml:lang="eng">The citrate-assisted growth of nickel hexacyanoferrate (NiHCF) nanocubes was investigated. Control over the complexation of Ni&lt;sup&gt;2+&lt;/sup&gt; ions with citrate at different temperatures enabled fine tuning of the nanocrystal (NC) dimensions and their self-assembly into mesocrystals. Our results introduce new concepts towards the synthesis of NiHCF NCs, potentially applicable to other members of the Prussian blue analogues family.</dcterms:abstract>
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